Ethanol → Phosphonium, diethyldiphenyl-, iodide

HRID 40425

반응식

HRID 40425 반응식
[C:1]1([PH:7][C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(=O)([O-])[O-].[K+].[K+].[CH2:20]([I:22])[CH3:21].[CH2:23](O)[CH3:24]>>[I-:22].[C:8]1([P+:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)([CH2:20][CH3:21])[CH2:23][CH3:24])[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1

참가 물질

5

반응물 4

HCID 702EthanolHCID 6340IodoethaneHCID 11430Potassium CarbonateHCID 70017Diphenylphosphine

생성물 1

HCID 357429Phosphonium, diethyldiphenyl-, iodide

실험 절차

50 g of diphenylphosphine were mixed with 150 ml of ethanol under nitrogen atmosphere. 37.12 g of potassium carbonate were then added to the mixture and the mixture was stirred. Finally, 125.73 g of ethyl iodide were added dropwise. After 48 hours at 50° C., the ethanol was removed. The product was then dissolved in chloroform. The chloroform was evaporated and the solid washed with diethyl ether and dried under vacuum. 98.45 g of diphenyl-diethyl-phosphonium iodide were obtained (98.5% wt. yield)

후처리

  1. customthe ethanol was removed
  2. dissolutionThe product was then dissolved in chloroform
  3. customThe chloroform was evaporated
  4. washthe solid washed with diethyl ether
  5. customdried under vacuum

출처 및 근거

ORD 기록
ord-1baf71ee64224c1ab66f12d9ce71dd4e
출처 데이터셋
uspto-grants-2013_09
특허 번호
US08529868B2

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