트리스(4-클로로페닐)포스핀

Tris(4-chlorophenyl)phosphine

HCID 70874CAS 1159-54-2

부분 구조 검색 유사 구조 찾기

기본 정보

표준 SMILES: Clc1ccc(P(c2ccc(Cl)cc2)c2ccc(Cl)cc2)cc1
InChIKey: IQKSLJOIKWOGIZ-UHFFFAOYSA-N
분자식: C18H12Cl3P
평균 분자량: 365.6 g/mol
단동위원소 질량: 363.97422

이름 및 식별자

우선 이름: Tris(4-chlorophenyl)phosphine
IUPAC: tris(4-chlorophenyl)phosphane
현지명: 트리스(4-클로로페닐)포스핀
영어명: Tris(4-chlorophenyl)phosphine
분자식: C18H12Cl3P
분자량: 365.62

이름 및 동의어

Tris(4-chlorophenyl)phosphine1159-54-2Phosphine, tris(4-chlorophenyl)-Tris(p-chlorophenyl)phosphinetri(p-Chlorophenyl)phosphinetri-(4-Chlorophenyl)phosphinePhosphine, tris(p-chlorophenyl)-EINECS 214-596-7DTXSID30151216Phosphine, tris[4-chlorophenyl]-NSC 136459RefChem:192104

이름 더 보기

트라이스(4-클로로페닐)수소화인트리스(4-클로로페닐)포스핀Tri(p-chlorophenTris(4-chlorophenyl)TRI(4-CHLOROPHENYL)PHOSPHINERIS(4-CHLOROPHENYL)PHOSPHINETris(p-chlorophenyl)phosphane

DTXCID9073707214-596-7IQKSLJOIKWOGIZ-UHFFFAOYSA-Ntris(4-chlorophenyl)phosphaneMFCD00013639NSC136459DWG5LE6Q8XNSC-136459

데이터베이스 식별자

CAS: 1159-54-2
PubChem CID: 70874
DTXSID: DTXSID30151216
UNII: DWG5LE6Q8X
EC Number: 214-596-7
Nikkaji: J203.418B

물성

구조 계산 물성

XLogP: 6.5
극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 0
회전 가능 결합 수: 3
무거운 원자 수: 22
형식 전하: 0
복잡도: 275

물리화학적 성질

녹는점: 100 · 100-103 °C (lit.)
끓는 점: 427.6 · 427.6±40.0 °C(Predicted)
저장 조건: Inert atmosphere,Room Temperature
물리적 상태: 수정 같은
색상: 하얀색
BRN: 751458 · 751458
InChI: 1S/C18H12Cl3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H
InChIKey: IQKSLJOIKWOGIZ-UHFFFAOYSA-N
SMILES: Clc1ccc(cc1)P(c2ccc(Cl)cc2)c3ccc(Cl)cc3

화학적 성질

white to light yellow crystal powde

안전 및 규제

GHS 분류

GHS Classification · 5건

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (97.8%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 46 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Hazard Classes and CategoriesSkin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (97.8%)

안전 데이터

wgk: 3
tsca: No
ridadr: 3278
HS 번호: 29310099
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-37/39
포장분류: III
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
스토리지 클래스: 11 - Combustible Solids

화학 및 산업

응용 분야 · 1건

용도Catalyst for:Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydesSolvent-free Heck reactionsCocatalyst in:Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagentsRhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenesRhodium-catalyzed hydrogenation reactionsPlatinum-catalyzed allylation reactions