Sodium aluminosilicate

HCID 72941443CAS 1344-00-9

기본 정보

표준 SMILES
O.[Al+3].[Al+3].[Na+].[Na+].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Si+4]
InChIKey
JYIMWRSJCRRYNK-UHFFFAOYSA-N
분자식
Al2H2Na2O7Si
평균 분자량
242.04 g/mol

개요

Sodium aluminosilicate is a fine white powder. Many ordinary rocks (feldspars) are aluminosilicates. Aluminosilicates with more open three-dimensional structures than the feldspars are called zeolites. The openings in zeolites appear as polyhedral cavities connected by tunnels. Zeolites act as catalysts by absorbing small molecules in their interior cavities and holding them in proximity so that reaction among them occurs sooner.

이름 및 식별자

우선 이름
Sodium aluminosilicate
IUPAC
dialuminum;disodium;hexakis(oxygen(2-));silicon(4+);hydrate

이름 및 동의어

DecalsoZeolexDecalso FAlusil ETVulkasil A 1Zeolex 23AZeolex 23PZeolex 25Zeolex 35Sodium silicoaluminateZeolex 100Sasil
이름 더 보기
Type A ZeoliteAmsr 3Degussa P820Valfor zeolite Na-a058TS43PSMAlusil SD533Zeolex 330Silicic acid, aluminum sodium salt

데이터베이스 식별자

CAS
1344-00-9
PubChem CID
72941443
UNII
058TS43PSM
EC Number
215-684-8

물성

구조 계산 물성

극성 표면적
7 Ų
수소 결합 공여자 수
1
수소 결합 수용자 수
7
회전 가능 결합 수
0
무거운 원자 수
12

실험 및 물리화학적 성질

Chemical ClassesMetals -> Metals, Inorganic Compounds
CosmeticsAbrasive; Viscosity controlling; Bulking
pH · 2건

Between 6,5 and 11,5 (5 % slurry)

6.5-10.5 (20% SLURRY)

OdorODORLESS
TasteTASTELESS
Food AdditivesANTICAKING AGENT OR FREE-FLOW AGENT, DRYING AGENT, FORMULATION AID, HUMECTANT -> FDA Substance added to food

안전 및 규제

GHS 분류

GHS Classification · 3건

This chemical does not meet GHS hazard criteria for 97.4% (559 of 574) of all reports.

Not Classified

Aggregated GHS information provided per 574 reports by companies from 6 notifications to the ECHA C&L Inventory.

유해성 정보

Regulatory Information · 5건

Chemical: Aluminosilicic acid, sodium salt

Regulation (EC) No 1831/2003 (amended)

Silicic acid, aluminum sodium salt is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silicic acid, aluminum sodium salt are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 01-09-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/15116

Silicic acid, aluminum sodium salt: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Aluminosilicic acid, sodium salt: Human health tier I assessment
Health HazardsACUTE/CHRONIC HAZARDS: Local irritant, low toxicity. (NTP, 1992)
Hazards SummaryA skin, eye, and mucous membrane irritant; [HSDB] A local irritant; [CAMEO] An irritant; [MSDSonline] See Aluminum.
FDA Requirements · 2건

121.101; LIMITATIONS: GRAS, ANTICAKING AGENT, UP TO 2%.

LIMITATIONS: 2% MAX IN SALT; 2% MAX IN SEASONING; 1% MAX IN SUGAR; 5% MAX IN BAKING POWDER. /SODIUM SILICOALUMINATE, PRECIPITATED HYDRATED/

Reactive GroupSalts, Basic

안전 및 보호

First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: If a spill of this chemical occurs, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with acetone and transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Personal Protective Equipment (PPE) · 1건

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

독성 정보

InteractionsNAAL SILICATES BOUND TOXIC CU, HG, & CD SALTS & DECREASED THEIR TOXICITY TO FISH & DAPHNIA BY >10-FOLD.
Environmental BiodegradationSODIUM ALUMINOSILICATE WAS SHOWN BY STUDIES WITH IN-LABELING & NEUTRON ACTIVATION ANALYSIS TO HAVE NO ADVERSE EFFECT ON THE CAPACITY OF TRICKLING FILTER OR ACTIVATED SLUDGE PLANTS.
Non-Human Toxicity Excerpts · 2건

NAAL SILICATES HAD VERY LOW TOXICITY TO ALGAE, MICROORGANISMS, DAPHNIA, FISH, TUBIFLEX, & MUSSELS EVEN @ VERY HIGH CONCN OF 250 MG/L HAD NO ACUTE TOXIC EFFECT ON ANIMALS.

Sodium aluminosilicate (SAS) was tested for mutagenicity in the Salmonella/microsome preincubation assay using a protocol approved by contractor of the National Toxicology Program. SAS was tested over a wide range of doses (0, 100, 333, 1000, 3333, and 4,000 ug/plate) in four Salmonella typhimurium strains (TA98, TA100, TA1535, and TA1537) in the presence and absence of Aroclor-induced rat or hamster liver S9. SAS was negative in these tests and the highest ineffective dose level tested (not causing the formation of a precipitate) in any Salmonella tester strain was 1000 ug/plate.

Environmental Water Concentrations · 1건

RATIOS OF OBSERVED NO-EFFECT CONCN OF ZEOLITE ON AQUATIC LIFE TO SURFACE WATER CONCN RANGE FROM >250->1000, INDICATING THAT THE PROPOSED USE AS A MONOPHOSPHATE BUILDER FOR DETERGENTS WOULD RESULT IN NO SIGNIFICANT ENVIRONMENTAL IMPACT AT EXPECTED USAGE LEVELS.

Toxicity DataLC (rat) > 140 mg/m3/4h

규제 정보

FDA Requirements · 2건

121.101; LIMITATIONS: GRAS, ANTICAKING AGENT, UP TO 2%.

LIMITATIONS: 2% MAX IN SALT; 2% MAX IN SEASONING; 1% MAX IN SUGAR; 5% MAX IN BAKING POWDER. /SODIUM SILICOALUMINATE, PRECIPITATED HYDRATED/

State Drinking Water Standards(CA) CALIFORNIA 1000 ug/l /Aluminum/
State Drinking Water Guidelines · 3건

(AZ) ARIZONA 73 ug/l /Aluminum/

(CA) CALIFORNIA 200 ug/l /Aluminum/

(ME) MAINE 1430 ug/l /Aluminum/

Federal Drinking Water GuidelinesEPA 50-200 ug/l /Aluminum/

화학 및 산업

약리 정보

Absorption, Distribution and Excretion · 1건

THE RATE & EXTENT OF URINARY EXCRETION OF SILICON WAS DETERMINED IN RATS AFTER ORAL ADMIN OF FOOD-GRADE SODIUM ALUMINOSILICATE. URINARY SILICON EXCRETION INCREASED RAPIDLY AFTER DOSING, & PEAK EXCRETION RATES OCCURRED WITHIN 24 HR IN ALL TEST GROUPS.

용도 및 제조

Uses · 4건

Used as food additive, anticaking agent, and in dentifrice; [HSDB] Natural form found in feldspars and zeolites; [CAMEO] Used in the production of leather, polymers, textiles, pulp & paper, paints & lacquers, cleaners & disinfectants, pesticides, food additives, and cosmetics; [IUCLID]

Pulp and Paper Processing [Category: Industry]

FOOD ADDITIVE, ANTICAKING AGENT

DENTIFRICE

U.S. Production2023: 10,000,000 - <50,000,000 lb
Consumer UsesProcessing aids not otherwise specified
Industry UsesNot Known or Reasonably Ascertainable
Formulations/PreparationsGRADES: TECHNICAL; FCC.
Household ProductsInformation on 129 consumer products that contain Sodium aluminosilicate in the following categories is provided:

관련 반응

9건

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