기본 정보
- 표준 SMILES
O.[Al+3].[Al+3].[Na+].[Na+].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Si+4]- InChIKey
JYIMWRSJCRRYNK-UHFFFAOYSA-N- 분자식
- Al2H2Na2O7Si
- 평균 분자량
- 242.04 g/mol
개요
Sodium aluminosilicate is a fine white powder. Many ordinary rocks (feldspars) are aluminosilicates. Aluminosilicates with more open three-dimensional structures than the feldspars are called zeolites. The openings in zeolites appear as polyhedral cavities connected by tunnels. Zeolites act as catalysts by absorbing small molecules in their interior cavities and holding them in proximity so that reaction among them occurs sooner.
이름 및 식별자
- 우선 이름
- Sodium aluminosilicate
- IUPAC
- dialuminum;disodium;hexakis(oxygen(2-));silicon(4+);hydrate
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
1344-00-9- PubChem CID
- 72941443
- UNII
- 058TS43PSM
- EC Number
- 215-684-8
물성
구조 계산 물성
- 극성 표면적
- 7 Ų
- 수소 결합 공여자 수
- 1
- 수소 결합 수용자 수
- 7
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 12
- 형식 전하
- 0
- 복잡도
- 0
실험 및 물리화학적 성질
pH
Between 6,5 and 11,5 (5 % slurry)
6.5-10.5 (20% SLURRY)
Solubility
Insoluble (NTP, 1992)
INSOL IN WATER, ALCOHOL, ORGANIC SOLVENTS; PARTIALLY SOL IN STRONG ACIDS & IN ALKALI HYDROXIDES @ 80-100 °C
Physical Description
Sodium aluminosilicate is a fine white powder. Many ordinary rocks (feldspars) are aluminosilicates. Aluminosilicates with more open three-dimensional structures than the feldspars are called zeolites. The openings in zeolites appear as polyhedral cavities connected by tunnels. Zeolites act as catalysts by absorbing small molecules in their interior cavities and holding them in proximity so that reaction among them occurs sooner.
Large Crystals; Dry Powder; Other Solid; Wet Solid
Fine white amorphous powder or beads
White odorless solid, insoluble in water; [Hawley]
안전 및 규제
GHS 분류
GHS Classification
This chemical does not meet GHS hazard criteria for 97.4% (559 of 574) of all reports.
Not Classified
Aggregated GHS information provided per 574 reports by companies from 6 notifications to the ECHA C&L Inventory.
유해성 정보
Regulatory Information
Chemical: Aluminosilicic acid, sodium salt
Regulation (EC) No 1831/2003 (amended)
Silicic acid, aluminum sodium salt is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silicic acid, aluminum sodium salt are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 01-09-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/15116
Silicic acid, aluminum sodium salt: Does not have an individual approval but may be used under an appropriate group standard
FDA Requirements
121.101; LIMITATIONS: GRAS, ANTICAKING AGENT, UP TO 2%.
LIMITATIONS: 2% MAX IN SALT; 2% MAX IN SEASONING; 1% MAX IN SUGAR; 5% MAX IN BAKING POWDER. /SODIUM SILICOALUMINATE, PRECIPITATED HYDRATED/
State Drinking Water Guidelines
(AZ) ARIZONA 73 ug/l /Aluminum/
(CA) CALIFORNIA 200 ug/l /Aluminum/
(ME) MAINE 1430 ug/l /Aluminum/
안전 및 보호
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
Nonfire Spill Response
SMALL SPILLS AND LEAKAGE: If a spill of this chemical occurs, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with acetone and transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
Personal Protective Equipment (PPE)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)
독성 정보
Non-Human Toxicity Excerpts
NAAL SILICATES HAD VERY LOW TOXICITY TO ALGAE, MICROORGANISMS, DAPHNIA, FISH, TUBIFLEX, & MUSSELS EVEN @ VERY HIGH CONCN OF 250 MG/L HAD NO ACUTE TOXIC EFFECT ON ANIMALS.
Sodium aluminosilicate (SAS) was tested for mutagenicity in the Salmonella/microsome preincubation assay using a protocol approved by contractor of the National Toxicology Program. SAS was tested over a wide range of doses (0, 100, 333, 1000, 3333, and 4,000 ug/plate) in four Salmonella typhimurium strains (TA98, TA100, TA1535, and TA1537) in the presence and absence of Aroclor-induced rat or hamster liver S9. SAS was negative in these tests and the highest ineffective dose level tested (not causing the formation of a precipitate) in any Salmonella tester strain was 1000 ug/plate.
Environmental Water Concentrations
RATIOS OF OBSERVED NO-EFFECT CONCN OF ZEOLITE ON AQUATIC LIFE TO SURFACE WATER CONCN RANGE FROM >250->1000, INDICATING THAT THE PROPOSED USE AS A MONOPHOSPHATE BUILDER FOR DETERGENTS WOULD RESULT IN NO SIGNIFICANT ENVIRONMENTAL IMPACT AT EXPECTED USAGE LEVELS.
규제 정보
FDA Requirements
121.101; LIMITATIONS: GRAS, ANTICAKING AGENT, UP TO 2%.
LIMITATIONS: 2% MAX IN SALT; 2% MAX IN SEASONING; 1% MAX IN SUGAR; 5% MAX IN BAKING POWDER. /SODIUM SILICOALUMINATE, PRECIPITATED HYDRATED/
State Drinking Water Guidelines
(AZ) ARIZONA 73 ug/l /Aluminum/
(CA) CALIFORNIA 200 ug/l /Aluminum/
(ME) MAINE 1430 ug/l /Aluminum/
화학 및 산업
약리 정보
Absorption, Distribution and Excretion
THE RATE & EXTENT OF URINARY EXCRETION OF SILICON WAS DETERMINED IN RATS AFTER ORAL ADMIN OF FOOD-GRADE SODIUM ALUMINOSILICATE. URINARY SILICON EXCRETION INCREASED RAPIDLY AFTER DOSING, & PEAK EXCRETION RATES OCCURRED WITHIN 24 HR IN ALL TEST GROUPS.
용도 및 제조
Uses
Used as food additive, anticaking agent, and in dentifrice; [HSDB] Natural form found in feldspars and zeolites; [CAMEO] Used in the production of leather, polymers, textiles, pulp & paper, paints & lacquers, cleaners & disinfectants, pesticides, food additives, and cosmetics; [IUCLID]
Pulp and Paper Processing [Category: Industry]
FOOD ADDITIVE, ANTICAKING AGENT
DENTIFRICE
Use Classification
Food additives
Food Additives -> ANTICAKING_AGENT -> JECFA Functional Classes
Food Additives -> ANTICAKING_AGENT -> JECFA Functional Classes
Food Additives -> ANTICAKING_AGENT -> JECFA Functional Classes
Food Additives -> ANTICAKING_AGENT -> JECFA Functional Classes
Cosmetics -> Abrasive; Viscosity controlling; Bulking
General Manufacturing Information
All Other Basic Inorganic Chemical Manufacturing
Silicic acid, aluminum sodium salt: ACTIVE
A SERIES OF HYDRATED SODIUM ALUMINUM SILICATES HAVING A NA2O:AL2O3:SIO2 MOLE RATIO OF APPROX 1:1:13.2.
USE OF ALUMINUM IN PROCESSING & STORING OF FOOD INCREASES ALUMINUM CONTENT, BUT NOT TO A TOXICOLOGICALLY SIGNIFICANT EXTENT. /ALUMINUM/
/BY ADDN OF SODIUM ALUMINUM SILICATES/...FORMULATION OF /SOME TRIAZINES/ CAN BE GREATLY FACILITATED & STABILITY OF THE PRODUCT DURING STORAGE ENHANCED. /SODIUM ALUMINUM SILICATES/
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