Styrene
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100-42-5C=Cc1ccccc1PPBRXRYQALVLMV-UHFFFAOYSA-N100-42-5、79637-11-9、98444-30-5DTXSID2021284CHEMBL285235CHEBI:27452안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
개요화학명은 비닐벤젠으로 일명 스티롤이라고도 한다. 무색의 액체이며 비중은 0.9로 물보다 낮고 비등점은 섭씨 1백45.1도, 인화점은 섭씨 32도이다. 유화제품을 크게 지방족탄화수소와 방향족탄화수소로 나누면 후자에 속하며 방향족의 벤젠계, 톨루엔계 크실렌계, 중벤젠계에 속하는 중간원료다.
용도폴리스틸렌, ABS, SBR 제조용으로 사용
개요Styrene has a characteristic, sweet, balsamic, almost floral odor that is extremely penetrating. Styrene occurs naturally in plants. It was first isolated from a resin called storax obtained from the inner bark of the Oriental sweet gum tree (Liquidambar orientalis) by Bonastre. In 1839, the German apothecary Eduard Simon prepared styrene by distilling it from storax and called it styrol. Simon observed it solidifi ed into a rubbery substance after being stored and believed it had oxidized into styrol oxide. Subsequent analysis showed the solid did not contain oxygen and it was renamed metastyrol. This was the first written record of polymerization in chemistry. In 1845, the English chemist, John Blyth, and the German chemist, August Wilhelm von Hofmann (1818 1892), observed that styrene was converted to polystyrene by sunlight and that styrene could be polymerized to polystyrene by heating in the absence of oxygen. It took another 70 years for the polymerization of styrene to be described by Hermann Staudinger (1881 1965) in the 1920s. This laid the foundation for the commercial polystyrene industry that developed in the 1930s.
용도메트포르민은 다낭성 난소 증후군치료에도 사용되며 다른 적응증도 연구중이다. 메트포르민은 간에서 포도당의 생성을 억제한다.
출처Reported found in cranberry and bilberry, currants, grape, parsley, milk and dairy products, whiskey, cocoa, coffee, tea, roasted filberts and roasted peanuts. Also reported found in fresh apple, guava fruit, pineapple, vinegar, butter, fish oil, black tea, roasted filbert, roasted peanut, soybean, plum brandy, apple brandy, Brazil nut, rice bran, Bourbon vanilla, grapes, peach, strawberry, onion, peas, bell pepper, cassia leaf, cheeses, parsley, milk, boiled and scrambled egg, lean fish, fish oil, cooked chicken and beef, rum, malt and Scotch whiskey, cider, grape, wine, cocoa, coffee, honey, cloudberry, plum, rose apple, beans, trassi, walnut, buckwheat, soursop, watercress, kiwifruit, wild rice, sapodilla fruit, nectarine, okra, crab, crayfish and pawpaw.
용도Styrene (monomer) is a viscous, highly flammable liquid that evaporates easily and polymerizes readily to polystyrene unless a stabilizer is added. Styrene is used in multiple industries, especially in reinforced plastics (e.g., fiberglass boats), and is widely used to make plastics and rubber, packaging materials (e.g., packing peanuts ), insulation for buildings, plastic pipes, food containers (e.g., takeout containers), and carpet backing) (ATSDR, 2010).
불러오는 중…
Styrene is a colorless or yellow, sweet odor liquid with a penetrating odor. It is produced during alkylation of benzene with ethylene. It is highly reactive and polymerizes rapidly with a violent explosive reaction. This demands proper handling, transportation, and storage by adding polymerization inhibitors in adequate quantities during these operations. Styrene monomer has been extensively used in the manufacture of chemical intermediates, fi lling components, plastics, resins, and stabilizing agents.
일반 설명A clear colorless to dark liquid with an aromatic odor. Flash point 90°F. Density 7.6 lb/gal. Vapors heavier than air and irritating to the eyes and mucous membranes. Subject to polymerization. If the polymerization takes place inside a closed container, the container may rupture violently. Less dense than water and insoluble in water. Used to make plastics, paints, and synthetic rubber.
스타이렌 단량체 제조를 위한 많은 기술들이 연구됨. 이들중 다음 방법들이 산업적 생산에 이용되어옴: 1) 에틸벤젠의 탈 수소반응; 2) 에틸벤젠이 에틸벤제 과산화수소(ethylbenzend hydroperoxide)로 산화되고 프로필렌과 반응하여 알파-페닐에탄올과 플로필렌 옥사이드가 생겨남. 이로부터 알콜이 탈수되어 스타이렌이 생성됨; 3) 아세토페논에 의한 에틸벤젠으로부터 알파-페닐에탄올로의 산화성 변환후 알콜의 탈수화; 4) 에틸벤젠의 곁사슬 염소화에 이은 탈수소염소화; 5) 에틸벤젠의 곁사슬 염소화와 이어 알콜로 가수분해된 다음 탈수에 의해 제조됨; 그리고 6) 석유의 열분해와 다양한 석유 공정으로부터의 회수. 첫번째 2 가지 방법은 스타이렌에 유일한 산업적으로 이용한 경로임 : 전체 지구 생산의 90 % 이상의 에틸벤젠의 탈수소화. 스타이렌으로의 2 가지 산업적 중요한 경로는 에틸렌과 결합한 벤젠의 알킬화에 의해 생산된 에틸벤젠을 기반으로 함
생산 방법Styrene is made by dehydrogenation of ethylbenzene at high temperature using metal catalysts: C6H5CH2CH2(g)→ C6H5CH = CH2(g) + H2(g). This is called the EB/SM (ethylbenzene/styrene monomer) process. Styrene can also be made by PO/SM (propylene oxide/styrene monomer) process). This process starts by oxidizing ethylbenzene (C6H5CH2CH2) to its hydroperoxide (C6H5CH(OOH)CH3), which is then used to oxidize propylene (CH3CH = CH2) to produce propylene oxide (CH3CH2CHO) and phenylethanol (C6H5CH(OH)CH3). The phenylethanol is then dehydrated to give styrene and water. Styrene can also be synthesized by reacting benzene and ethylene or natural gas.
Prepared from ethylbenzene or from phenylethanol.
정의ChEBI: A vinylarene that is benzene carrying a vinyl group. It has been isolated from the benzoin resin produced by Styrax species.