CAS 1184-58-3 Chlorodimethylaluminum (HCID 79147)

이름 및 식별자

우선 이름: Chlorodimethylaluminum
IUPAC: chloro(dimethyl)alumane
현지명: 디메틸 알루미늄 클로라이드
영어명: DIMETHYLALUMINUM CHLORIDE
분자식: C2H6AlCl
분자량: 92.5

이름 및 동의어

Aluminum, chlorodimethyl-Dimethylaluminum chloride1184-58-3ChlorodimethylaluminumDimethylaluminium chlorideDTXSID5061580B548L3505QRefChem:134299DTXCID2033449214-668-8DimethylchloroaluminumAluminum,chlorodimethyl-

이름 더 보기

디메틸알루미늄클로라이드DimethylaluminumDimethylchloralaneDimethylchloroalanechlorodimethyl-aluminuDimethylaluminiumchloridAluminiumdimethylchloride

chloro(dimethyl)alumaneUNII-B548L3505QEINECS 214-668-8Chlorodi(methyl)alumaneSCHEMBL5443Dimethylaluminum chloride, 97%AKOS009156843NS00081566

데이터베이스 식별자

CAS: 1184-58-3
PubChem CID: 79147
DTXSID: DTXSID5061580
EC Number: 214-668-8

물성

구조 계산 물성

극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 0
회전 가능 결합 수: 0
무거운 원자 수: 4
형식 전하: 0
복잡도: 13

실험 및 물리화학적 성질

Physical Description · 2건

Liquid; CBI

White liquid; [Merck Index]

물리화학적 성질

녹는점: -21 °C · -21°C
끓는 점: 126 · 126-127°C
밀도: 0.701 g/mL · 0.701 g/mL at 25 °C
증기압: 79 mmHg · 79 mmHg ( 60 °C)
인화점: 1 °F · −1 °F
저장 조건: 0 · 0-6°C
용해도: sol most organic solvents; stable in alkanes or arenes
물리적 상태: 액체
Specific Gravity: 0.71 · 0.71
InChI: InChI=1S/2CH3.Al.ClH/h2*1H3;;1H/q;;+1;/p-1
InChIKey: JGHYBJVUQGTEEB-UHFFFAOYSA-M
SMILES: [Al](Cl)(C)C
EPA: Aluminum, chlorodimethyl- (1184-58-3)

화학적 성질

Clear colorless liquid

안전 및 규제

GHS 분류

GHS Classification · 5건

Danger

H225 (53.5%): Highly Flammable liquid and vapor [Danger Flammable liquids]；H250 (100%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]；H260 (100%): In contact with water releases flammable gases which may ignite spontaneously [Danger Substances and mixtures which in contact with water, emit flammable gases]；H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H318 (53.5%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

P210, P222, P223, P231, P231+P232, P233, P240, P241, P242, P243, P260, P264, P264+P265, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P363, P370+P378, P402+P404, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 86 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory Information · 3건

Chemical: Aluminium, chlorodimethyl-

Aluminum, chlorodimethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Aluminum, chlorodimethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Dimethylaluminium chloride: HSNO Approval: HSR006292 Approved with controls

Other Safety InformationIMAP assessments - Aluminium, chlorodimethyl-: Environment tier I assessment；IMAP assessments - Aluminium, chlorodimethyl-: Human health tier I assessment

Hazards Summary · 1건

Reacts violently with water; Corrosive and pyrophoric; [Merck Index] Pyrophoric; Reacts violently with water evolving flammable gases; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Sigma-Aldrich MSDS] See Trimethylaluminum, Methyl aluminum sesquibromide, and Chlorodiethylaluminum.

Hazard Classes and CategoriesFlam. Liq. 2 (53.5%)；Pyr. Liq. 1 (100%)；Water-react. 1 (100%)；Skin Corr. 1B (100%)；Eye Dam. 1 (53.5%)

독성 정보

Adverse EffectsDermatotoxin - Skin burns.；Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors.

규제 정보

Regulatory Information · 3건

Chemical: Aluminium, chlorodimethyl-

Aluminum, chlorodimethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Aluminum, chlorodimethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Dimethylaluminium chloride: HSNO Approval: HSR006292 Approved with controls

안전 데이터

wgk: 2
tsca: TSCA listed
ridadr: UN 3394 4.2/PG 1
HS 번호: 29319090
risk_code: 14/15-17-23/24/25-34-67-65-62-51/53-48/20-11
hazard_code: F,C,N
safety_code: 16-26-36/37/39-45-27-43-9
포장분류: I
위험 등급: 4.2
기존화학 물질: 2015-3-6513

화학 및 산업

용도 및 제조

UsesUsed as a reagent and catalyst in organic chemistry; [Merck Index]

U.S. Production2023: 1,000,000 - <8,500,000 lb；2022: 1,000,000 - <8,500,000 lb；2021: 1,000,000 - <8,500,000 lb；2020: 1,000,000 - <8,500,000 lb

Industry UsesCBI；Catalyst

General Manufacturing Information · 2건

CBI；Pesticide, Fertilizer, and Other Agricultural Chemical Manufacturing

Aluminum, chlorodimethyl-: ACTIVE

응용 분야

용도Dimethylaluminum Chloride is used as a strong Lewis acid that can also act as a proton scavenger; reacts with HX to give methane and MeAlClX.

상·하류 제품 정보

하류 제품

공급사58 곳

阿诺西（上海）生物技术有限公司400-1107768 15058188853 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]

杭州品高化工有限公司0571-87658025 · [email protected]

苏州市森菲达化工有限公司18796480002 18796480002 · [email protected]

화합물 노트

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