1,1'-(Methylenedi-p-phenylene)bismaleimide (HCID 83648)

이름 및 식별자

우선 이름: 1,1'-(Methylenedi-p-phenylene)bismaleimide
IUPAC: 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione
현지명: 4,4'-디페닐메탄 비스-말린이미드
영어명: Bismaleimide
분자식: C21H14N2O4
분자량: 358.35

이름 및 동의어

1,1'-(Methylenedi-p-phenylene)bismaleimideRefChem:409135Bismaleimide13676-54-54,4'-BismaleimidodiphenylmethaneBismaleimide S1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis-4,4'-Methylenebis(N-phenylmaleimide)p,p'-DimaleimidodiphenylmethaneBis(4-maleimidophenyl)methaneDiphenylmethanebismaleimide1,1'-(Methylenedi-4,1-phenylene)bismaleimide

이름 더 보기

4,4""""-디페닐메탄비스-말린이미드4,4'-디페닐메탄비스-말린이미드4,4'-디페닐메탄비스-말린이미드(4,4'-DIPHENYLMETHANEBIS-MALEIMIDE)BMIbismaleimidesBismaleimide, 4,4'-diphenylmethane1,1’-(methylenedi-1,4-phenylene)bis-1H-pyrrole-2,5-dione1-(4-[4-(2,5-Dioxo-2,5-dihydro-1H-pyrrol-1-yl)benzyl]phenyl)-1H-pyrrole-2,5-dionexu292amb-3000

p,p'-Methylenebis(N-phenylmaleimide)Bis(p-maleimidophenyl)methane1,1'-(Methylenebis(4,1-phenylene))bis(1H-pyrrole-2,5-dione)4,4'-Dimaleimidodiphenylmethane4,4'-Diphenylmethanedimaleimide4,4'-Biphenylmethanebismaleimide4,4'-DiphenylmethanebismaleimideN,N'-Bismaleimido-4,4'-diphenylmethane

데이터베이스 식별자

CAS: 13676-54-5
PubChem CID: 83648
DTXSID: DTXSID8044381
ChEMBL: CHEMBL478304
UNII: I67AL345KM
EC Number: 237-163-4
Nikkaji: J208.092C

물성

구조 계산 물성

XLogP: 2.1
극성 표면적: 74.8 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 4
회전 가능 결합 수: 4
무거운 원자 수: 27
형식 전하: 0
복잡도: 614

실험 및 물리화학적 성질

Physical DescriptionDry Powder; Other Solid

Collision Cross Section · 1건

174.3 Å² [M-H]- [CCS Type: DT; Buffer gas: N2; Ionization: ESI-; Dataset: TOXCAST; Source Identifier: DTXSID8044381]；182.7 Å² [M+Na]+ [CCS Type: DT; Buffer gas: N2; Ionization: ESI+; Dataset: TOXCAST; Source Identifier: DTXSID8044381]；197.5 Å² [M+H]+ [CCS Type: DT; Buffer gas: N2; Ionization: APCI+; Dataset: TOXCAST; Source Identifier: DTXSID8044381]

물리화학적 성질

녹는점: 156 · 156-158 °C(lit.)
끓는 점: 490.79 °C · 490.79°C (rough estimate)
밀도: 1.336 · 1.3360 (rough estimate)
증기압: 0 Pa · 0Pa at 25℃
굴절률: 1.68 · 1.6800 (estimate)
저장 조건: Sealed in dry,Room Temperature
용해도: 물(약간 용해됨)
물리적 상태: powder to crystal
산도 계수 (pKa): -0.4 · -0.40±0.20(Predicted)
색상: Light yellow to Amber to Dark green
수용성: 물에 불용성.
BRN: 333986 · 333986
InChI: 1S/C21H14N2O4/c24-18-9-10-19(25)22(18)16-5-1-14(2-6-16)13-15-3-7-17(8-4-15)23-20(26)11-12-21(23)27/h1-12H,13H2
InChIKey: XQUPVDVFXZDTLT-UHFFFAOYSA-N
SMILES: O=C1C=CC(=O)N1c2ccc(Cc3ccc(cc3)N4C(=O)C=CC4=O)cc2
LogP: 1.5 at · 1.5 at 25℃
NIST: p,p'-Bis(N-maleimidophenyl)methane(13676-54-5)
EPA: 1 H-Pyrrole-2,5-dione, · 1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis- (13676-54-5)

화학적 성질

yellow to brownish fine crystalline powder

안전 및 규제

GHS 분류

GHS Classification · 5건

Danger

H315 (78.7%): Causes skin irritation [Warning Skin corrosion/irritation]；H317 (12%): May cause an allergic skin reaction [Warning Sensitization, Skin]；H319 (76.4%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H330 (87.8%): Fatal if inhaled [Danger Acute toxicity, inhalation]；H335 (76.2%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P260, P261, P264, P264+P265, P271, P272, P280, P284, P302+P352, P304+P340, P305+P351+P338, P316, P319, P320, P321, P332+P317, P333+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 648 reports by companies from 14 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory Information · 4건

Chemical: 1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis-

1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 13-05-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/11119

1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazard Classes and CategoriesSkin Irrit. 2 (78.7%)；Skin Sens. 1A (12%)；Eye Irrit. 2 (76.4%)；Acute Tox. 2 (87.8%)；STOT SE 3 (76.2%)

규제 정보

Regulatory Information · 4건

Chemical: 1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis-

1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 13-05-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/11119

1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

안전 데이터

wgk: 2
tsca: TSCA listed
rtecs: ON5670000
ridadr: UN 2811 6.1/PG 2
HS 번호: 29251900
risk_code: 23-36/37/38
hazard_code: T
safety_code: 26-45-37/39
포장분류: III
위험 등급: 6.1
기존화학 물질: KE-23911
Hazard Classifications: Acute Tox. 2 InhalationEye Irrit. 2Skin Irrit. 2STOT SE 3
스토리지 클래스: 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials

화학 및 산업

용도 및 제조

U.S. Production2023: 313,612 lb；2022: 130,706 lb；2021: 163,633 lb；2020: 164,398 lb

Consumer UsesOther

Industry UsesIntermediate；Monomers

General Manufacturing Information · 2건

Rubber Product Manufacturing；Plastics Material and Resin Manufacturing

1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis-: ACTIVE

응용 분야

용도Bismaleimide products can be used to make bismaleimide resins, modified phenolic resins, modified epoxy thermosetting resins such as heat resistance and PP, PVC, PBT, PMMA and other plastics, as well as high-grade rubber products.

일반 설명The thermal and mechanical properties of GEEA cured by 1,1′-(methylenedi-4,1-phenylene)bismaleimide were studied.