트리 -tert- 부틸 포스 핀

Tris(1,1-dimethylethyl)phosphine

HCID 83681CAS 13716-12-6

부분 구조 검색 유사 구조 찾기

기본 정보

표준 SMILES: CC(C)(C)P(C(C)(C)C)C(C)(C)C
InChIKey: BWHDROKFUHTORW-UHFFFAOYSA-N
분자식: C12H27P
평균 분자량: 202.32 g/mol
단동위원소 질량: 202.18503749

이름 및 식별자

우선 이름: Tris(1,1-dimethylethyl)phosphine
IUPAC: tritert-butylphosphane
현지명: 트리 -tert- 부틸 포스 핀
영어명: Tri-tert-butylphosphine
분자식: C12H27P
분자량: 202.32

이름 및 동의어

Tri-tert-butylphosphine13716-12-6Tris(1,1-dimethylethyl)phosphineEINECS 237-266-4DTXSID80160090RefChem:900102DTXCID4082581237-266-4tri-t-Butylphosphinetritert-butylphosphanetri-tert-butylphosphanePhosphine, tris(1,1-dimethylethyl)-

이름 더 보기

트리-tert-부틸포스핀TTBPTri-tert-butyLButylphosphineri-tert-butylphosphineUncle Ding JilinTri-t-butylphosphosphin

tri-Tertbutylphosphinetri(tert-butyl)phosphineTRIS(TERT-BUTYL)PHOSPHINEPtBu3tBu3PMFCD00015006Tri-tert-butylphosphine,TTBPP(T-BU)3

데이터베이스 식별자

CAS: 13716-12-6
PubChem CID: 83681
DTXSID: DTXSID80160090
UNII: BH6Z6Z4K6W
EC Number: 237-266-4
Nikkaji: J278.010K

물성

구조 계산 물성

XLogP: 2.9
극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 0
회전 가능 결합 수: 3
무거운 원자 수: 13
형식 전하: 0
복잡도: 128

실험 및 물리화학적 성질

SpringerMaterials PropertiesSchoenflies notation

물리화학적 성질

녹는점: 30 · 30-35 °C(lit.)
끓는 점: 102 · 102-103 °C13 mm Hg(lit.)
밀도: 0.861 g/mL · 0.861 g/mL at 25 °C
인화점: 1 °F · 1 °F
저장 조건: Flammables area
물리적 상태: 고체
Specific Gravity: 0.68 · 0.68
수용성: 불용성
BRN: 1738613 · 1738613
InChI: InChI=1S/C12H27P/c1-10(2,3)13(11(4,5)6)12(7,8)9/h1-9H3
InChIKey: BWHDROKFUHTORW-UHFFFAOYSA-N
SMILES: P(C(C)(C)C)(C(C)(C)C)C(C)(C)C
NIST: Tri-tert-butylphosphine(13716-12-6)

화학적 성질

Colorless to light yellow liqui

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H250 (98.2%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]

P210, P222, P231, P233, P260, P264, P264+P265, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P370+P378, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 57 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazard Classes and CategoriesPyr. Liq. 1 (98.2%)

안전 데이터

wgk: 3
ridadr: UN 2846 4.2/PG 1
HS 번호: 29319090
risk_code: 17-34-67-65-63-48/20-11
hazard_code: F,C
safety_code: 26-45-62-36/37/39-25-43-27-16
포장분류: I
위험 등급: 4.2
기존화학 물질: 2010-3-4569
F 고인화성물질: 10-19-23
Hazard Classifications: Carc. 2Eye Dam. 1Flam. Liq. 2Pyr. Liq. 1Skin Corr. 1BSTOT SE 3
스토리지 클래스: 4.2 - Pyrophoric and self-heating hazardous materials

화학 및 산업

응용 분야 · 1건

용도Tri-tert-butylphosphine is used primarily in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

상·하류 제품 정보

상류 원료

하류 제품

1-(4-Pyridyl)piperazine Benzenamine, 4-methoxy-N,N-bis(4-methoxyphenyl)-1-(3-피리디닐)피페라진 N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine 3,6-디페닐-9H-카바졸 Methanesulfonato[di-t-butyl(n-butyl)phosphine](2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane 트리 -t- 부틸 포스 포늄 테트라 플루오로 보레이트

공급사50 곳

衢州润东化工有限公司0570-8789886 18892685668 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

T&W GROUP021-61551611 13296011611 · [email protected]

北京安司莫森技术有限公司010-82954736 13391601435 · [email protected]

上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]

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