2-니트로디페닐아민

2-Nitrodiphenylamine

HCID 8407CAS 119-75-5

기본 정보

표준 SMILES
O=[N+]([O-])c1ccccc1Nc1ccccc1
InChIKey
RUKISNQKOIKZGT-UHFFFAOYSA-N
분자식
C12H10N2O2
평균 분자량
214.22 g/mol
단동위원소 질량
214.07422756

개요

2-nitrodiphenylamine appears as red-brown crystalline powder or reddish-brown solid. (NTP, 1992)

이름 및 식별자

우선 이름
2-Nitrodiphenylamine
IUPAC
2-nitro-N-phenylaniline
현지명
2-니트로디페닐아민
영어명
2-Nitrodiphenylamine
분자식
C12H10N2O2
분자량
214.22

이름 및 동의어

2-Nitrodiphenylamine119-75-52-Nitro-N-phenylanilineBenzenamine, 2-nitro-N-phenyl-o-(Phenylamino)nitrobenzeneCCRIS 6075DTXSID4025749EINECS 204-348-6N-Phenyl-2-nitrobenzenamineAI3-08882DTXCID7057492-nitro-n-phenylbenzeneamine
이름 더 보기
2-나이트로디페닐아민2-니트로디페닐아민NitrodiphenylamineO-NITRO DIPHENYLAMINENSC 4754NSC 629274NSC 105613c.i. 10335Sudan Yellow 1339TIMTEC-BB SBB000544
PHENYL 2-NITROPHENYLAMINEoNitrodiphenylaminePHENYL(2-NITROPHENYL)AMINENPhenylonitroanilineoNitroNphenylaniline2NitroNphenylanilineDiphenylamine, 2nitroRefChem:88722

데이터베이스 식별자

CAS
119-75-5
PubChem CID
8407
DTXSID
DTXSID4025749
ChEMBL
CHEMBL1450018
UNII
DT9NA7ZDD8
EC Number
204-348-6
Nikkaji
J37.804F

물성

구조 계산 물성

XLogP
3.7
극성 표면적
57.9 Ų
수소 결합 공여자 수
1
수소 결합 수용자 수
3
회전 가능 결합 수
2
무거운 원자 수
16

실험 및 물리화학적 성질

Chemical ClassesNitrogen Compounds -> Nitroanilines
SpringerMaterials PropertiesBoiling point
Density1.36 @25 °C
Solubility · 2건

less than 1 mg/mL at 72 °F (NTP, 1992)

1.1 [ug/mL] (The mean of the results at pH 7.4)

Melting Point · 2건

167.9 °F (NTP, 1992)

75.5 °C

Physical Description · 3건

2-nitrodiphenylamine appears as red-brown crystalline powder or reddish-brown solid. (NTP, 1992)

CBI; Liquid

Orange solid; [Reference #1] Reddish-brown solid; [CAMEO] Red or orange crystalline solid; [Alfa Aesar MSDS]

물리화학적 성질

녹는점
74 · 74-76 °C(lit.)
끓는 점
346 °C · 346 °C
밀도
1.36 · 1.36
증기 밀도
10.7 · 10.7 (vs air)
굴절률
1.666 · 1.6660 (estimate)
인화점
346 °C · 346°C

화학적 성질

Red Crystalline Solid

안전 및 규제

GHS 분류

GHS Classification · 4건

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 60 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 3건

Chemical: Benzenamine, 2-nitro-N-phenyl-

Benzenamine, 2-nitro-N-phenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzenamine, 2-nitro-N-phenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Benzenamine, 2-nitro-N-phenyl-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

DOT LabelPoison
Fire HazardsFlash point data for this chemical are not available; however, it is probably combustible. (NTP, 1992)
Health HazardsSYMPTOMS: Symptoms of exposure to this chemical include irritation of the skin, eyes, mucous membranes and upper respiratory tract. Structurally similar chemicals may cause methemoglobinemia.
Hazards SummaryA skin, eye, mucous membrane, and upper respiratory tract irritant; May cause methemoglobinemia, based on structurally similar compounds; [NTP] A skin and strong eye irritant; [Alfa Aesar MSDS] See Otto fuel.
Reactive GroupAmines, Phosphines, and Pyridines

안전 및 보호

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. A water spray may also be used. (NTP, 1992)
First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: If a spill of this chemical occurs, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with acetone and transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:
Protective Action Criteria (PAC) · 3건

12 [mg/m3]

130 [mg/m3]

790 [mg/m3]

Personal Protective Equipment (PPE) · 1건

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

독성 정보

Adverse EffectsMethemoglobinemia - The presence of increased methemoglobin in the blood; the compound is classified as secondary toxic effect
EPA Provisional Peer-Reviewed Toxicity Values · 3건

2-Nitrodiphenylamine

PDF Document

2011

안전 데이터

wgk
3
tsca
TSCA listed
HS 번호
29214400
risk_code
36/37/38
hazard_code
Xi
safety_code
26-36-37/39

화학 및 산업

용도 및 제조

Uses · 1건

Used to control the combustion of propylene glycol dinitrate in Otto fuel II (US navy propellant for torpedoes and other weapons systems); Also used as a solvent dye; [ATSDR Public Health Statements] Used as stabilizer for nitroglycerin and as a chemical intermediate; [NTP]

U.S. Production2023: <75,000 lb
Industry UsesOther
General Manufacturing Information · 2건

All Other Chemical Product and Preparation Manufacturing

Benzenamine, 2-nitro-N-phenyl-: ACTIVE

응용 분야 · 3건

용도(2-Nitrophenyl)phenylamine (cas# 119-75-5) is a compound useful in organic synthesis.

용도2-Nitrodiphenylamine is used to control the combustion of propylene glycol dinitrate in Otto fuel II (US navy propellant for torpedoes and other weapons systems); Also used as a solvent dye; Used as stabilizer for nitroglycerin and as a chemical intermediate

일반 설명Red-brown crystalline powder or reddish-brown solid.

공급사50 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
南京凯美西化工有限公司02558748998 18951874644 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]

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