2-Nitrodiphenylamine → N-Phenyl-o-phenylenediamine

HRID 1970683

반응식

HRID 1970683 반응식
[CH:1]1[CH:6]=[CH:5][C:4]([NH:7][C:8]2[C:13]([N+:14]([O-])=O)=[CH:12][CH:11]=[CH:10][CH:9]=2)=[CH:3][CH:2]=1.[H][H]>[Pd].C(O)C>[C:4]1([NH:7][C:8]2[C:13]([NH2:14])=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:3]=[CH:2][CH:1]=[CH:6][CH:5]=1

참가 물질

5

반응물 2

HCID 84072-NitrodiphenylamineHCID 178418361HCID 178418361, 화합물

생성물 1

HCID 68297N-Phenyl-o-phenylenediamine

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 702Ethanol용매

실험 절차

To a pressure reaction bottle was added 10 g 2-nitrodiphenylamine, 0.5 g 5% palladium on carbon and 100 ml 95% ethanol. The mixture was hydrogenated at 22 C and 40 psi hydrogen for 2 hours. Following filtration through celite and solvent removal, an oil was obtained that crystallized on standing.

후처리

  1. customTo a pressure reaction bottle
  2. filtrationfiltration through celite and
  3. customsolvent removal
  4. customan oil was obtained
  5. customthat crystallized

출처 및 근거

ORD 기록
ord-1265ef5e45b947489999c77d64f792c9
출처 데이터셋
uspto-grants-2013_04
특허 번호
US08431045B2

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