트리스(트리페닐포스핀)로듐(I) 염화물

Chlorotris(triphenylphosphine)rhodium(I)

HCID 84599CAS 14694-95-2

기본 정보

표준 SMILES: [Cl-].[Rh].c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1
InChIKey: QBERHIJABFXGRZ-UHFFFAOYSA-M
분자식: C54H45ClP3Rh-
평균 분자량: 925.2 g/mol

개요

See also: Tris(triphenylphosphine) rhodium (I) chloride (annotation moved to); (SP-4-2)-Chlorotris(triphenylphosphine)rhodium (annotation moved to).

이름 및 식별자

우선 이름: Chlorotris(triphenylphosphine)rhodium(I)
IUPAC: rhodium;tris(triphenylphosphane);chloride
현지명: 트리스(트리페닐포스핀)로듐(I) 염화물
영어명: Tris(triphenylphosphine)chlororhodium
분자식: C54H45ClP3Rh
분자량: 925.21

이름 및 동의어

14694-95-2Chlorotris(triphenylphosphine)rhodium(I)Tris(triphenylphosphine)rhodium(I) chlorideWilkinson's catalystChlorotris(triphenylphosphine)rhodium16592-65-7rhodium;triphenylphosphane;chlorideTris(triphenylphosphine)chlororhodiumMFCD00010016Tris(triphenylphosphine)rhodium (I) chlorideTris(triphenylphosphine)rhodium chlorideTris(triphenylphosphine)chlororhodium(I)

이름 더 보기

트리스(트리페닐포스핀)로듐(I)염화물트리스(트리페닐포스핀)로듐(I)염화물(TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)CHL...WilkinsonRhCl(PPh3)3Wilkinson’s catalyst(SP-4-2)-Chlorotris(triphenylphosphine)rhodiumTris(triphenylphosphine)rhodiu

0FV534BKEVRhodium, chlorotris(triphenylphosphine)-, (SP-4-2)-Wilkinson inverted exclamation mark s catalystC54H45ClP3RhUNII-0FV534BKEVWilkinson CatalystEINECS 238-744-5Tris(triphenylphosphino)chlororhodium

데이터베이스 식별자

CAS: 14694-95-2
PubChem CID: 84599
DTXSID: DTXSID30893902
UNII: 0FV534BKEV

물성

구조 계산 물성

극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 9
무거운 원자 수: 59
형식 전하: -1
복잡도: 202

물리화학적 성질

녹는점: 245 · 245-250 °C (dec.)
끓는 점: 170 °C · >170°C
밀도: 1.363 · 1.363; d 1.379
증기압: 0 Pa · 0Pa at 25℃
저장 조건: Keep in dark place,Inert atmosphere,Room temperature
용해도: 2 · 대부분의 용매(예: 벤젠, 에탄올, 에 용해됨클로로포름, 디클로로메탄)에 용해되지만 포스핀이 해리됩니다. 용액에서 O{2}와 반응
물리적 상태: 결정성 분말
색상: 적갈색에서 적갈색까지
수용성: 불용성
Merck: 14 · 14,9758
BRN: 4581440 · 4581440
InChI: 1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1
InChIKey: QEYYHUJFSQCTAE-UHFFFAOYSA-M
SMILES: Cl[Rh].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
LogP: 5.69 at · 5.69 at 20℃
NIST: chlorotris(triphenylphosphine)rhodium(14694-95-2)
EPA: Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)- (14694-95-2)

화학적 성질

magenta crystals

안전 및 규제

안전 데이터

wgk: 1
tsca: TSCA listed
ridadr: 1759
HS 번호: 28439090
risk_code: 34-36/38
hazard_code: C,Xi
safety_code: 22-24/25-37/39-28A-26-15-45-36/37/39
F 고인화성물질: 8-10-23
Hazard Classifications: Aquatic Chronic 4Skin Sens. 1
스토리지 클래스: 11 - Combustible Solids

화학 및 산업

응용 분야 · 1건

용도Tris(triphenylphosphine)rhodiu is also known as Wilkinson's catalyst and is commonly used to catalyze the hydrogenation of alkenes. Tris(triphenylphosphine)rhodiu is also used in the catalytic hydroboration of alkenes with catecholborane and pinacolborane and the selective 1,4-reduction of α, β-unsaturated carbonyl compounds.