기본 정보
- 표준 SMILES
C1=CCCC1- InChIKey
LPIQUOYDBNQMRZ-UHFFFAOYSA-N- 분자식
- C5H8
- 평균 분자량
- 68.12 g/mol
- 단동위원소 질량
- 68.06260026
개요
Cyclopentene appears as a colorless liquid. Less dense than water and insoluble in water. Flash point below 0 °F. Vapors heavier than air. Inhalation of high concentrations may be narcotic. Used to make rubber and plastics.
이름 및 식별자
- 우선 이름
- Cyclopentene
- IUPAC
- cyclopentene
- 현지명
- 사이클로펜텐
- 영어명
- Cyclopentene
- 분자식
- C5H8
- 분자량
- 68.12
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
142-29-0- PubChem CID
- 8882
- DTXSID
DTXSID6029171- ChEMBL
CHEMBL1797299- ChEBI
CHEBI:49155- UNII
- ONM2CKV81Z
- EC Number
- 205-532-9
- Nikkaji
- J34.912G
물성
구조 계산 물성
- XLogP
- 1.9
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 0
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 5
- 형식 전하
- 0
- 복잡도
- 38
실험 및 물리화학적 성질
Chemical Classes
Other Classes -> Aliphatics, Unsaturated
Flammable agents - 3rd degree
Physical Description
Cyclopentene appears as a colorless liquid. Less dense than water and insoluble in water. Flash point below 0 °F. Vapors heavier than air. Inhalation of high concentrations may be narcotic. Used to make rubber and plastics.
Liquid
Colorless liquid; [CAMEO] Odor like gasoline; [FAHG] Slightly sweetish odor; [Alfa Aesar MSDS]
물리화학적 성질
- 녹는점
- 135 °C · −135 °C(lit.)
- 끓는 점
- 44 · 44-46 °C(lit.)
- 밀도
- 0.771 g/mL · 0.771 g/mL at 25 °C(lit.)
- 증기압
- 20.89 psi · 20.89 psi ( 55 °C)
- 굴절률
- 20 · n20/D 1.421(lit.)
- 인화점
- 30 °F · <−30 °F
- 저장 조건
- 0 · 0-6°C
- 용해도
- 25 °C에서 · 물: 25°C에서 용해성0.535g/L
- 물리적 상태
- 액체
- Specific Gravity
- 0.771 · 0.771
- 색상
- 무색의
- 수용성
- 섞일 수 없음
- 비열
- 1.8 J/ · Cp(liquid): 1.8 J/(g·K), at 25℃
- BRN
- 635707 · 635707
- Henry's Law Constant
- 6.3 x · 6.3 x 10-2 atmm3/mol at 25 °C (Hine and Mookerjee, 1975)
- 안정성
- 안정적인. 가연성이 높습니다. 강한 산화제와 호환되지 않습니다. 차갑게 보관하세요.
- InChI
- 1S/C5H8/c1-2-4-5-3-1/h1-2H,3-5H2
- InChIKey
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N
- SMILES
- C1CC=CC1
- LogP
- 2.47 at · 2.47 at 25℃
- NIST
- Cyclopentene(142-29-0)
- EPA
- Cyclopentene (142-29-0)
화학적 성질
Cyclopentene is a highly flammable liquid with a low flash point. It reacts readily with oxidizing agents.
안전 및 규제
GHS 분류
GHS Classification
Danger
H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]
P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P270, P271, P273, P280, P301+P316, P301+P317, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P317, P319, P321, P330, P331, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 190 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Danger
H225: Highly Flammable liquid and vapor [Danger Flammable liquids]
유해성 정보
Regulatory Information
Chemical: Cyclopentene
Cyclopentene is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Cyclopentene are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 25-02-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/27532
Cyclopentene: Does not have an individual approval but may be used under an appropriate group standard
The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
Fire Hazards
Special Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flashback. Explosion may occur under fire condition. (USCG, 1999)
· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Health Hazards
May be harmful by inhalation, ingestion, or skin absorption. May cause eye and skin irritation. (USCG, 1999)
CAUTION: Petroleum crude oil (UN1267) may contain TOXIC hydrogen sulphide gas.
Hazards Summary
May polymerize; High vapor concentrations may have narcotic effects; [CAMEO] May cause smarting and reddening of skin if spilled and allowed to remain on clothes; High vapor concentrations may cause mild smarting of eyes and respiratory system, dizziness, and loss of consciousness; [CHRIS] An irritant that can cause skin burns on prolonged contact; [FAHG] May form explosive peroxides; An irritant; Harmful by ingestion (may cause lung damage by aspiration); Inhalation may cause dizziness or drowsiness; Harmful by ingestion and skin absorption; [Alfa Aesar MSDS] See 1-Pentene.
Reactivity Profile
CYCLOPENTENE may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions.
DOT Hazard Classification
Cyclopentene
UN2246
Class 3 Flammable and combustible liquid (49 eCFR § 173.120)
PG II: the degree of danger presented by the material is medium
Peroxide Forming Chemical
Cyclopentene
B: Compounds that form peroxides on concentration (distillation/evaporation)
Clark
안전 및 보호
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
First Aid
INHALATION: Call a physician. If inhaled, remove victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
General First Aid:
Isolation and Evacuation
Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:
Immediate precautionary measure
독성 정보
안전 데이터
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- GY5950000
- ridadr
- UN 2246
- 독성
- Acute oral LD50 for rats is 1,656 mg/kg (quoted, RTECS, 1985).
- HS 번호
- 29021990
- risk_code
- 11-21/22-36/37/38-65-67-52/53-38
- hazard_code
- F,Xn
- safety_code
- 9-16-26-33-36-62-61-36/37
- 포장분류
- II
- 위험 등급
- 3
- 기존화학 물질
- KE-09303
- F 고인화성물질
- 10-23
- 자연 발화 온도
- 743 °F
- Hazard Classifications
- Acute Tox. 4 DermalAcute Tox. 4 OralAsp. Tox. 1Flam. Liq. 2Skin Irrit. 2
- 스토리지 클래스
- 3 - Flammable liquids
화학 및 산업
용도 및 제조
General Manufacturing Information
Petrochemical Manufacturing
Cyclopentene: ACTIVE
응용 분야
용도Cyclopentene is a cycloalkene that is cyclopentane having one endocyclic double bond. Vapors heavier than air. Inhalation of high concentrations may be narcotic. Used to make rubber and plastics. Neopentyl phosphine ligand catalyzed Heck coupling of cyclopentene has been reported. Mechanism of reaction of ground state oxygen atom with cyclopentene has been investigated. Homopolymerization of cyclopentene has been reported. Photocatalytic oxidation of cyclopentene over various titanium(IV) oxide catalyst has been reported. Cyclopentene was used to investigate the [2+2] cycloaddition of diamond (001) surfaces with alkene.
일반 설명Cyclopentene appears as a colorless liquid. Less dense than water and insoluble in water. Flash point below 0°F. Vapors heavier than air. Inhalation of high concentrations may be narcotic. Used to make rubber and plastics.
제조 방법
Cyclopentene is synthesized by selective hydrogenation of cyclopentadiene or by dehydration of cyclopentanol. It is produced industrially in large amounts by steam cracking of naphtha. Cyclopentene is present in coal tar, cigarette smoke, and automobile emissions.
상·하류 제품 정보
상류 원료
하류 제품
공급사50 곳
추가 설명
정의ChEBI: Cyclopentene is a cycloalkene that is cyclopentane having one endocyclic double bond.
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