Isopropanol → Trichlorocyclopentylsilane
반응식
[CH:1]1[CH2:5][CH2:4][CH2:3][CH:2]=1.[Cl:6][SiH:7]([Cl:9])[Cl:8].C(O)(C)C>[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl>[CH:1]1([Si:7]([Cl:9])([Cl:8])[Cl:6])[CH2:5][CH2:4][CH2:3][CH2:2]1참가 물질
5
반응 조건
- 온도
- 150 °C
실험 절차
In a 100 ml autoclave were charged 13.5 g (0.198 mole) of cyclopentene, 24.4 g (0.180 mole) of trichlorosilane and 25 μl of a 0.077 m mole/ml chloroplatinic acid solution in isopropyl alcohol (platinum content 1.92×10-6 mole), which were then stirred at 150° C. for 30 minutes. Cyclopentyl trichlorosilane was obtained quantitatively.
출처 및 근거
- ORD 기록
- ord-db48ca45905a4ffa943827bd251f129c
- 출처 데이터셋
- uspto-grants-1993_09
- 특허 번호
- US05248803
반응 노트
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