Acryloylmorpholine (HCID 98723)

이름 및 식별자

우선 이름: Acryloylmorpholine
IUPAC: 1-morpholin-4-ylprop-2-en-1-one
현지명: 아크릴로일 모폴린
영어명: 4-Acryloylmorpholine
분자식: C7H11NO2
분자량: 141.17

이름 및 동의어

5117-12-4acryloylmorpholineACRYLOYL MORPHOLINE4-(1-oxo-2-propenyl)-morpholineDTXSID0044947K0Y58P61JANSC-1622212-Propen-1-one, 1-(4-morpholinyl)-DTXCID8024947RefChem:1076142418-140-1610-626-1

이름 더 보기

아크릴로일모폴린아크릴로일몰포린1-(4-모폴리닐)-2-프로펜-1-온아크릴로일 모폴린1-(모폴린-4-일)프로펜온4-(1-옥소-2-프로펜일)모폴린4-아크릴로일모폴린N-아크릴로일모폴린4-아크릴로일모르폴린ACMOyyyy-m-d4-AcryLAcrylmorpholideAcryloylmorpholin

4-Acryloylmorpholine1-Morpholinoprop-2-en-1-oneN-AcrylylmorpholineN-AcryloylmorpholineMorpholine, 4-(1-oxo-2-propenyl)-1-(Morpholin-4-yl)prop-2-en-1-one1-morpholin-4-ylprop-2-en-1-one4-(1-Oxo-2-propenyl)morpholine

데이터베이스 식별자

CAS: 5117-12-4
PubChem CID: 98723
DTXSID: DTXSID0044947
ChEMBL: CHEMBL3187188
UNII: K0Y58P61JA
EC Number: 418-140-1、610-626-1
Nikkaji: J87.318G

물성

구조 계산 물성

XLogP: -0.1
극성 표면적: 29.5 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 2
회전 가능 결합 수: 1
무거운 원자 수: 10
형식 전하: 0
복잡도: 139

물리화학적 성질

녹는점: 35 °C · −35 °C(lit.)
끓는 점: 158 °C · 158°C 50mm
밀도: 1.122 g/mL · 1.122 g/mL at 25 °C(lit.)
증기압: 1.03 · 1.03-1.64Pa at 25-29.9℃
굴절률: 20 · n20/D 1.512(lit.)
인화점: 230 °F · >230 °F
저장 조건: 2 · 2-8°C
용해도: 물에 용해됨
물리적 상태: 액체
산도 계수 (pKa): -1.08 · -1.08±0.20(Predicted)
색상: 무색~황색
수용성: 1000 g/L · 1000g/L at 20℃
BRN: 119302 · 119302
화장품 원료 기능: 가소제
InChI: 1S/C7H11NO2/c1-2-7(9)8-3-5-10-6-4-8/h2H,1,3-6H2
InChIKey: XLPJNCYCZORXHG-UHFFFAOYSA-N
SMILES: C=CC(=O)N1CCOCC1
LogP: -0.46 at · -0.46 at 20.5-21℃
NIST: N-acryloylmorpholine(5117-12-4)
EPA: 4 · Morpholine, 4-(1-oxo-2-propenyl)- (5117-12-4)

화학적 성질

4-Acryloylmorpholine has a melting point of 35 °C and is clear liquid at room temperature. At 25 °C, it has a density of 1.122 g/mL. It needs to be stored at 2-8°C.

안전 및 규제

GHS 분류

GHS Classification · 6건

Danger

H302: Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P264, P264+P265, P270, P272, P280, P301+P317, P302+P352, P305+P354+P338, P317, P319, P321, P330, P333+P317, P362+P364, and P501 (click each P-code to see the statement)

Danger

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P264, P264+P265, P270, P271, P272, P280, P301+P317, P302+P352, P304+P340, P305+P354+P338, P316, P317, P319, P321, P330, P333+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

유해성 정보

Regulatory Information · 4건

Chemical: Morpholine, 4-(1-oxo-2-propenyl)-

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: No longer Valid Update: 10-11-2008 https://echa.europa.eu/registration-dossier/-/registered-dossier/9420

Acryloyl morpholine: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationEvaluation - Morpholine, 4-(1-oxo-2-propenyl)- (acryloyl morpholine)

Hazard Classes and Categories · 5건

Acute Tox. 4 (100%)

Acute toxicity - category 4

Acute toxicity (Oral) - Category 4

Acute Tox. 4 *

안전 데이터

wgk: 2
tsca: TSCA listed
HS 번호: 29349990
risk_code: 22-41-43-48/22
hazard_code: Xn
safety_code: 23-26-36/37/39
기존화학 물질: 2000-3-1524
Hazard Classifications: Acute Tox. 4 OralEye Dam. 1Skin Sens. 1STOT RE 2 Oral
스토리지 클래스: 10 - Combustible liquids

화학 및 산업

용도 및 제조

General Manufacturing Information2-Propen-1-one, 1-(4-morpholinyl)-: ACTIVE

응용 분야 · 3건

용도접착제, 자외선 경화 수지, 산업용 코팅, UV 인쇄 잉크, 오일 회수 폴리머, 의약 및 필수 화학 물질에 사용됩니다.

개요4-Acryloylmorpholine (4-AM) is a water-soluble monomer, an acrylamide derivative containing a heterocyclic tetrahydrooxazine substituent. Homo- and copolymers of 4-АМ have several valuable properties. They are soluble both in water and in many organic solvents such as alcohols, chloroform, tetrahydrofuran, and dioxane, are non-toxic, and are used for solid-phase synthesis of peptides in chromatography, as materials for composite semipermeable membranes, in catalysis, and for biomedical purposes. Various functional groups are introduced into poly-4-AM to expand its application fields. Random copolymers of 4-АМ with carboxylic acids (acrylic, 4-pentenoic, undecenoic, 2-acrylamido-2-methyl-1-propanesulfonic), behaving as anionic polyelectrolytes, and copolymers with N-hydroxysuccinimide ester of acrylic acid, acting as polymeric carriers, have been synthesized[2-3].

용도4-Acryloylmorpholine is used in adhesives, UV curable resins, industrial coatings, UV printing ink, oil recovery polymer, medicinal and commodity chemicals.