2-Naphthalenecarboxylic acid, 1-hydroxy-, methyl ester → HCID 22126290, 화합물

HRID 1005161

반응식

HRID 1005161 반응식
[OH:1][C:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[CH:5]=[CH:4][C:3]=1[C:12]([O:14][CH3:15])=[O:13].[CH3:16][O:17][CH2:18][CH2:19]Br>>[CH3:16][O:17][CH2:18][CH2:19][O:1][C:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[CH:5]=[CH:4][C:3]=1[C:12]([O:14][CH3:15])=[O:13]

참가 물질

3

반응물 2

HCID 703582-Naphthalenecarboxylic acid, 1-hydroxy-, methyl esterHCID 809722-Bromoethyl methyl ether

생성물 1

HCID 22126290HCID 22126290, 화합물

실험 절차

By alkylating methyl 1-hydroxy-naphthalene-2-carboxylate analogously to Example 1 (g) with 2-bromoethyl methyl ether there was obtained methyl 1-(2-methoxy-ethoxy)-naphthalene-2-carboxylate, which was subsequently converted analogously to Example 5 (b)-(c) firstly into [1-(2-methoxy-ethoxy)-naphthalen-2-yl]-methanol and then into 2-chloromethyl-1-(2-methoxy-ethoxy)-naphthalene, which was finally obtained as a beige solid; MS: 250 (M)+.

출처 및 근거

ORD 기록
ord-ec1ba080094845c7805ff815c90d503a
출처 데이터셋
uspto-grants-2000_04
특허 번호
US06051712

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