Water → HCID 18791126, 화합물

HRID 1005347

반응식

HRID 1005347 반응식
[CH2:1]([C:3]1[CH:16]=[C:15]([CH2:17][CH3:18])[C:14]2[S:13][C:12]3[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=3)[C:6](=[O:19])[C:5]=2[CH:4]=1)[CH3:2].[BH4-].[Na+].O>CO>[CH2:1]([C:3]1[CH:16]=[C:15]([CH2:17][CH3:18])[C:14]2[S:13][C:12]3[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=3)[CH:6]([OH:19])[C:5]=2[CH:4]=1)[CH3:2]

참가 물질

5

반응물 3

HCID 962WaterHCID 1228252,4-DiethylthioxanthoneHCID 4311764Sodium borohydride

생성물 1

HCID 18791126HCID 18791126, 화합물수율 99.3%

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

To a stirred solution of 2,4-diethyl-9H-thioxanthen-9-one (20 g, 74.5 mmol) in methanol (400 ml) cooled in an ice bath was added sodium borohydride (8 g, 0.2 mole) portionwise. After 1 hour at room temperature, water (100 ml) was added to the reaction mixture and the precipitate collected and washed with water to give the title compound as a white solid (20 g).

후처리

  1. customthe precipitate collected
  2. washwashed with water

출처 및 근거

ORD 기록
ord-c97341537da64b47bc474f8f2b95fa97
출처 데이터셋
uspto-grants-2000_04
특허 번호
US06054448

연결된 노트

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