Benzene → Benzaldehyde

HRID 1030019

반응식

HRID 1030019 반응식
[CH:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:7]1[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1.[H][H].[CH:17]([OH:20])(C)C>>[CH2:17]([OH:20])[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH:7](=[O:20])[C:14]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1.[C:10]1([C:9]2[CH:8]=[CH:3][CH:2]=[CH:1][CH:6]=2)[CH:11]=[CH:12][CH:13]=[CH:14][CH:7]=1

참가 물질

7

반응물 4

HCID 241BenzeneHCID 3776IsopropanolHCID 9266CyclooctaneHCID 178418361HCID 178418361, 화합물

생성물 3

HCID 240BenzaldehydeHCID 244Benzyl AlcoholHCID 7095Biphenyl

실험 절차

The experimental procedure was substantially the same as in Example 1 except that the amount of benzene as the starting hydrocarbon compound was decreased to 12 ml while 13.8 ml of isopropyl alcohol were replaced with 18 ml of cyclooctane as the hydrogen donor compound. The result of the analysis of the reaction mixture after completion of the reaction was that the molar yields of benzyl alcohol, benzaldehyde and biphenyl were 6624%, 350% and 8%, respectively, based on the molar amount of the rhodium complex used as the catalyst. Small amounts of cyclooctane carbaldehyde and cyclooctanemethanol were detected in the reaction mixture.

후처리

  1. customThe result of the analysis of the reaction mixture after completion of the reaction

출처 및 근거

ORD 기록
ord-3b78011df78045d6b31e32042433843d
출처 데이터셋
uspto-grants-1992_04
특허 번호
US05104504

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