참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Hydrochloric Acid | HCID 313 | — |
| 반응물 | Vinylamine | HCID 11642 | — |
| 반응물 | Ammonium Hydroxide | HCID 14923 | — |
| 반응물 | Vinylpyrrolidone-vinylamine copolymer | HCID 197374 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | N-vinyl-2-pyrrolidone | HCID 6917 | — |
| 생성물 | N-Vinylformamide | HCID 83191 | — |
반응 단계
20 g of N-vinylpyrrolidone and 2 g of N-vinylformamide were polymerized in 120 ml of water, to which 1 ml of NH4OH solution was added, at 80° C. under a blanket of argon. Initiator α,α'-azoisobutyronitrile 110 mg, polymerization time 24 h. 145 ml of concentrated hydrochloric acid were added to the resulting aqueous copolymer solution, and the mixture was refluxed (110° C.) for 7 h. The mixture was subsequently worked up as described in A using a strongly basic ion exchanger. 160 g of aqueous solution of an N-vinylamine/N-vinylpyrrolidone copolymer with an N-vinylamine content of 5.7% by weight were then obtained. The solids content of the polymer solution was 9.53%, the pH was 10.1, and the reduced viscosity of the polymer was determined as 1.61 dl/g (measured on a 1% strength solution in H2O at 25° C.).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US05106740 |
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| 출처 데이터셋 | uspto-grants-1992_04 |
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| ORD ID | ord-acea7afff9d14b1298d1d413e3df4fab |
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| 출처 메모 | uspto-grants-1992_04 |
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