돌아가기
Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 1030461생성일: 2026년 10월 26일

Hydrochloric Acid → N-vinyl-2-pyrrolidone

https://huagongshe.com/reaction/1030461

반응식

참여 물질

역할이름HCID투입량
반응물Hydrochloric AcidHCID 313—
반응물VinylamineHCID 11642—
반응물Ammonium HydroxideHCID 14923—
반응물Vinylpyrrolidone-vinylamine copolymerHCID 197374—
용매WaterHCID 962—
생성물N-vinyl-2-pyrrolidoneHCID 6917—
생성물N-VinylformamideHCID 83191—

반응 조건

온도110 °C

반응 단계

20 g of N-vinylpyrrolidone and 2 g of N-vinylformamide were polymerized in 120 ml of water, to which 1 ml of NH4OH solution was added, at 80° C. under a blanket of argon. Initiator α,α'-azoisobutyronitrile 110 mg, polymerization time 24 h. 145 ml of concentrated hydrochloric acid were added to the resulting aqueous copolymer solution, and the mixture was refluxed (110° C.) for 7 h. The mixture was subsequently worked up as described in A using a strongly basic ion exchanger. 160 g of aqueous solution of an N-vinylamine/N-vinylpyrrolidone copolymer with an N-vinylamine content of 5.7% by weight were then obtained. The solids content of the polymer solution was 9.53%, the pH was 10.1, and the reduced viscosity of the polymer was determined as 1.61 dl/g (measured on a 1% strength solution in H2O at 25° C.).

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US05106740
출처 데이터셋uspto-grants-1992_04
ORD IDord-acea7afff9d14b1298d1d413e3df4fab
출처 메모uspto-grants-1992_04