Hydrochloric Acid → Methyldiisopropylchlorosilane

HRID 1033912노트

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HRID 1033912 반응식
[ClH:1].[CH3:2][SiH:3]([CH:7]([CH3:9])[CH3:8])[CH:4]([CH3:6])[CH3:5]>>[CH3:2][Si:3]([CH:7]([CH3:9])[CH3:8])([CH:4]([CH3:6])[CH3:5])[Cl:1]

참가 물질

3

반응물 2

HCID 313Hydrochloric Acid3회HCID 101621268Diisopropyl(methyl)silane

생성물 1

HCID 6421633Methyldiisopropylchlorosilane

반응 조건

온도
100 °C

실험 절차

A thermometer, hydrogen chloride gas inlet tube, and reflux condenser were fitted to a stirrer-equipped 200 mL four-neck flask, and 100 g methyldiisopropylsilane was then introduced into the flask. This was followed by the addition of 0.01 g platinum/divinyltetramethyldisiloxane complex and heating to 100° C. Hydrogen chloride gas was then introduced into the mixture. The introduction of hydrogen chloride gas was suspended after 4 hours. Distillation at ambient pressure yielded 122 g methyldiisopropylchlorosilane (purity≥99%, bp=146° C.). The methyldiisopropylchlorosilane yield was 97%.

후처리

  1. customwere fitted to a stirrer-equipped 200 mL four-neck flask
  2. additionThis was followed by the addition of 0.01 g platinum/divinyltetramethyldisiloxane complex
  3. distillationDistillation at ambient pressure

출처 및 근거

ORD 기록
ord-7b8adb2b15ea4227ace872254c168764
출처 데이터셋
uspto-grants-1994_05
특허 번호
US05312949

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