3-(2-Methylpropenyl)benzonitrile → 3-Isobutylbenzonitrile

HRID 1034045

반응식

HRID 1034045 반응식
[CH3:1][C:2]([CH3:12])=[CH:3][C:4]1[CH:5]=[C:6]([CH:9]=[CH:10][CH:11]=1)[C:7]#[N:8]>CO.[Pd]>[CH2:3]([C:4]1[CH:5]=[C:6]([CH:9]=[CH:10][CH:11]=1)[C:7]#[N:8])[CH:2]([CH3:12])[CH3:1]

참가 물질

4

반응물 1

HCID 190247923-(2-Methylpropenyl)benzonitrile

생성물 1

HCID 190247553-Isobutylbenzonitrile수율 94%

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 887Methanol용매

반응 조건

온도
25 °C

실험 절차

To a solution of 3-(2-methyl-1-propenyl)benzonitrile (5.80 g) in methanol (50 ml) was added 10% palladium on activated carbon (1 g), and the mixture was stirred under hydrogen atmosphere (3 atm) at 25° C. for 1 hour. The catalyst was filtered off and the liltrate was evaporated to give 3-isobutylbenzonitrile (5.52 g) as a pale yellow oil.

후처리

  1. filtrationThe catalyst was filtered off
  2. customthe liltrate was evaporated

출처 및 근거

ORD 기록
ord-f5fee2c5150e427682aeaa078f4e5058
출처 데이터셋
uspto-grants-1994_05
특허 번호
US05312829

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