Didecylamine → HCID 178443398, 화합물

HRID 1051154노트

반응식

HRID 1051154 반응식
[CH2:1]([NH:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[Br-].[Br:23][C:24]1[CH:25]=[CH:26][C:27]2[C:36]([CH:37]=1)=[S+:35][C:34]1[C:29](=[CH:30][CH:31]=[C:32](Br)[CH:33]=1)[N:28]=2>C(Cl)(Cl)Cl>[Br-:23].[CH2:12]([N:11]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[C:24]1[CH:25]=[CH:26][C:27]2[C:36]([CH:37]=1)=[S+:35][C:34]1[C:29](=[CH:30][CH:31]=[C:32]([N:11]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])[CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH:33]=1)[N:28]=2)[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21]

참가 물질

4

반응물 2

HCID 14261DidecylamineHCID 162132753,7-Dibromophenothiazin-5-ium bromide

생성물 1

HCID 178443398HCID 178443398, 화합물

시약·촉매·용매 1

HCID 6212Chloroform용매

실험 절차

To a solution of 1.7 g (5.72 mmol) of didecylamine in 20 mL of CHCl3 was added 0.63 g (1.43 mmol) of 22. The reaction mixture was stirred at room temperature for 2 h under argon and concentrated under diminished pressure to give 3,7-bis(didecylamino)phenothiazin-5-ium bromide (CPD-14): mass spectrum (MALDI-TOF), m/z 788.69 (M+).

후처리

  1. concentrationconcentrated under diminished pressure

출처 및 근거

ORD 기록
ord-908db483963e4e948e5a0e4b787928c1
출처 데이터셋
uspto-grants-2016_07
특허 번호
US09388163B2

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