Methyldichlorosilane → Hexylmethyldichlorosilane

HRID 1068507

반응식

C(P(CCCC)CCCC)CCC.Cl[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[CH3:21][SiH:22]([Cl:24])[Cl:23]>>[Cl:23][Si:22]([Cl:24])([CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])[CH3:21]

참가 물질

반응물 3

HCID 6376Methyldichlorosilane

HCID 109921-Chlorohexane

HCID 13831Tributylphosphine

생성물 1

HCID 84650Hexylmethyldichlorosilane수율 16.7%

실험 절차

In the same apparatus and procedure as Example 1 above, 0.15 g (0.75 mmol) of tri-n-butylphosphine, 0.90 g (7.5 mmol) of 1-chlorohexane, and 3.90 ml (37.5 mmol) of methyldichlorosilane were reacted at 150° C. for 12 hrs. The resulting mixture was distilled to give 0.25 g of 2,2-dichloro-2-silaoctane (yield:16%).

후처리

distillationThe resulting mixture was distilled

출처 및 근거

ORD 기록: ord-a4b61707bd094a13bf1dbeeff4eb633f
출처 데이터셋: uspto-grants-2001_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06251057B1

연결된 노트

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