Methylhydroquinone → Methyl-1,4-benzoquinone

HRID 1074900

반응식

HRID 1074900 반응식
[CH3:1][C:2]1[CH:8]=[C:7]([OH:9])[CH:6]=[CH:5][C:3]=1[OH:4].Cl[O-]>C(Cl)(Cl)Cl>[CH3:1][C:2]1[C:3](=[O:4])[CH:5]=[CH:6][C:7](=[O:9])[CH:8]=1

참가 물질

4

반응물 2

HCID 7253MethylhydroquinoneHCID 61739Hypochlorite

생성물 1

HCID 11122Methyl-1,4-benzoquinone

시약·촉매·용매 1

HCID 6212Chloroform용매

실험 절차

2-methyl hydroquinone (1b) of 3.0 g (24 mmol) is dissolved in 150 ml of chloroform, wherein 100 ml each of hypochloride solution which have been so prepared as mentioned above are added and each reaction is made in the same way as described in Example 1, and then 2-methyl benzoquinone (IIb) is obtained. Table below shows the yields of isolation corresponding to each case of the investigation:

후처리

  1. additionabove are added

출처 및 근거

ORD 기록
ord-054885253cbc4b59beba4cc150ab1079
출처 데이터셋
uspto-grants-1983_07
특허 번호
US04394315

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