Cyclohexane-1,1-dicarboxylic acid → Bis-1,4-dioxanemethanol cyclohexanedicarboxylate

HRID 1075758

반응식

HRID 1075758 반응식
[C:1]1([C:10]([OH:12])=[O:11])([C:7]([OH:9])=[O:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[O:13]1[CH2:18][CH2:17][O:16][CH2:15][CH:14]1[CH2:19][OH:20]>C([Sn](=O)CCCC)CCC.C1(C)C(C)=CC=CC=1>[C:1]1([C:10]([OH:12])=[O:11])([C:7]([OH:9])=[O:8])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]1.[O:13]1[CH2:18][CH2:17][O:16][CH2:15][CH:14]1[CH2:19][OH:20].[O:13]1[CH2:14][CH2:15][O:12][CH2:10][CH:1]1[CH2:7][OH:9]

참가 물질

5

반응물 2

HCID 136906Cyclohexane-1,1-dicarboxylic acidHCID 12655091(1,4-Dioxan-2-yl)methanol

생성물 1

HCID 68139332Bis-1,4-dioxanemethanol cyclohexanedicarboxylate수율 91%

시약·촉매·용매 2

HCID 61221Dibutyltin oxide촉매HCID 7237O-Xylene용매

실험 절차

Following the procedure of Example 2, a mixture of 172 grams (1.0 mole) of cyclohexane dicarboxylic acid, 265.5 grams (2.25 moles) of 1,4-dioxanemethanol, 75 milliliters of xylene and 0.3 gram of dibutyltin oxide catalyst yields a gray waxy product in 91 percent yield. Recrystallization from an ethanol-water mixture gives the colorless bis-1,4-dioxanemethanol cyclohexanedicarboxylate.

후처리

  1. customyields a gray waxy product in 91 percent yield
  2. customRecrystallization from an ethanol-water mixture

출처 및 근거

ORD 기록
ord-8073c10b678940bd836cb23a7b0ba6d5
출처 데이터셋
uspto-grants-1976_05
특허 번호
US03954742

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