Methylhydrazine → HCID 12582663, 화합물

HRID 1075930노트

반응식

HRID 1075930 반응식
[C:1]([N:9]1[CH2:19][CH2:18][C:12]2[N:13]=[N:14][C:15](S)=[CH:16][C:11]=2[CH2:10]1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:20][NH:21][NH2:22]>>[C:1]([N:9]1[CH2:19][CH2:18][C:12]2[N:13]=[N:14][C:15]([N:21]([CH3:20])[NH2:22])=[CH:16][C:11]=2[CH2:10]1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

참가 물질

3

반응물 2

HCID 6061MethylhydrazineHCID 178519528HCID 178519528, 화합물

생성물 1

HCID 12582663HCID 12582663, 화합물

실험 절차

A solution of 3.4 g of 6-benzoyl-5,6,7,8-tetrahydro-3-mercaptopyrido[4,3-c]pyridazine in 40 cc of methylhydrazine is stirred at a bath temperature of 110° for 11/2 hours. The oil obtained after concentrating the mixture in a vacuum is taken up in absolute ethanol, and the calculated amount of gentisic acid is added. After standing for some time the crystalline bisgentisinate of the title compound is obtained. M.P. 166°-168° (decomp.).

후처리

  1. customThe oil obtained
  2. concentrationafter concentrating the mixture in a vacuum
  3. additionthe calculated amount of gentisic acid is added
  4. customis obtained

출처 및 근거

ORD 기록
ord-fb60c9f91cac448ca2feea80af9814d7
출처 데이터셋
uspto-grants-1976_05
특허 번호
US03954754

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