4-Ethyl-4'-iodobiphenyl → HCID 19428732, 화합물

HRID 1079108

반응식

HRID 1079108 반응식
[C:1]1([CH3:30])[CH:6]=[CH:5][C:4]([NH:7][C:8]2[CH:13]=[CH:12][C:11]([C:14]3[CH:27]=[CH:26][C:17]([NH:18][C:19]4[CH:24]=[CH:23][C:22]([CH3:25])=[CH:21][CH:20]=4)=[C:16]([CH3:28])[CH:15]=3)=[CH:10][C:9]=2[CH3:29])=[CH:3][CH:2]=1.[CH2:31]([C:33]1[CH:38]=[CH:37][C:36]([C:39]2[CH:44]=[CH:43][C:42](I)=[CH:41][CH:40]=2)=[CH:35][CH:34]=1)[CH3:32]>>[C:1]1([CH3:30])[CH:2]=[CH:3][C:4]([N:7]([C:42]2[CH:43]=[CH:44][C:39]([C:36]3[CH:37]=[CH:38][C:33]([CH2:31][CH3:32])=[CH:34][CH:35]=3)=[CH:40][CH:41]=2)[C:8]2[CH:13]=[CH:12][C:11]([C:14]3[CH:27]=[CH:26][C:17]([N:18]([C:4]4[CH:5]=[CH:6][C:1]([CH3:30])=[CH:2][CH:3]=4)[C:19]4[CH:24]=[CH:23][C:22]([C:25]5[CH:13]=[CH:12][C:11]([CH2:14][CH3:15])=[CH:10][CH:9]=5)=[CH:21][CH:20]=4)=[C:16]([CH3:28])[CH:15]=3)=[CH:10][C:9]=2[CH3:29])=[CH:5][CH:6]=1

참가 물질

3

반응물 2

HCID 154778284-Ethyl-4'-iodobiphenylHCID 19428741HCID 19428741, 화합물

생성물 1

HCID 19428732HCID 19428732, 화합물수율 23.7%

실험 절차

According to the same manner as that described in Synthesis Example 1, 14.9 g of N,N'-diacetyl-3,3'-dimethylbenzidine was reacted with 21.8 g of para-iodobenzene to give N,N'-di-p-tolyl-3,3'-dimethylbenzidine. Further, 12.0 g of N,N'-di-p-tolyl-3,3'-dimethylbenzidine was reacted with 15.4 g of 4-ethyl-4'-iodobiphenyl according to the same manner as that described in Synthesis Example 1 to give N,N'-di-p-tolyl-N,N'-di(4'-ethylbiphenyl-4-yl)-3,3'-dimethylbenzidine (hereinafter referred to as 6-c) (8.82 g, yield: 23.7%).

후처리

  1. customthat described in Synthesis Example 1

출처 및 근거

ORD 기록
ord-8f99adbaebd0477fa6dbca77655fc277
출처 데이터셋
uspto-grants-1996_08
특허 번호
US05550290

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