Sulfuric Acid → HCID 131716827, 화합물

HRID 1085382

반응식

HRID 1085382 반응식
[S:1](=[O:5])(=[O:4])([OH:3])O.[C:6]1([C:12]2[C:13]([C:18]3[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=3)=[CH:14][CH:15]=[CH:16][CH:17]=2)[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1>O>[C:18]1([C:13]2[C:12]([C:6]3[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=3)=[CH:17][CH:16]=[CH:15][CH:14]=2)[CH:23]=[CH:22][C:21]([S:1]([OH:5])(=[O:4])=[O:3])([S:1]([OH:3])(=[O:5])=[O:4])[CH2:20][CH:19]=1

참가 물질

4

반응물 2

HCID 1118Sulfuric AcidHCID 6766O-Terphenyl

생성물 1

HCID 131716827HCID 131716827, 화합물

시약·촉매·용매 1

HCID 962Water용매

반응 조건

온도
140 °C

실험 절차

880 g of concentrated sulfuric acid were heated to 110° C, and 270.5 g of terphenyl were added. The temperature was raised to 140° C and left on that level for 4 hours. After cooling down to 100° C, 800 ml of water were added dropwise, and the mixture was allowed to cool and then filtered with suction, giving a crude product which was used direct in the next stage. Purity (HPLC): 99.7%; yield: 565 g.

후처리

  1. temperatureAfter cooling down to 100° C
  2. temperatureto cool
  3. filtrationfiltered with suction

출처 및 근거

ORD 기록
ord-2042710a350c43b99826428d2aed046a
출처 데이터셋
uspto-grants-1991_04
특허 번호
US05008472

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