Benzotrichloride → N,N'-Bis[4-(2-ethylhexyl)oxycarbonylphenyl]benzamidine

반응식

[NH2:1][C:2]1[CH:18]=[CH:17][C:5]([C:6]([O:8][CH2:9][CH:10]([CH2:15][CH3:16])[CH2:11][CH2:12][CH2:13][CH3:14])=[O:7])=[CH:4][CH:3]=1.Cl[C:20](Cl)(Cl)[C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1>>[CH2:15]([CH:10]([CH2:11][CH2:12][CH2:13][CH3:14])[CH2:9][O:8][C:6]([C:5]1[CH:4]=[CH:3][C:2]([NH:1][C:20](=[N:1][C:2]2[CH:3]=[CH:4][C:5]([C:6]([O:8][CH2:9][CH:10]([CH2:15][CH3:16])[CH2:11][CH2:12][CH2:13][CH3:14])=[O:7])=[CH:17][CH:18]=2)[C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)=[CH:18][CH:17]=1)=[O:7])[CH3:16]

참가 물질

반응물 2

HCID 7367Benzotrichloride

HCID 114366142-Ethylhexyl 4-aminobenzoate

생성물 1

HCID 15734503N,N'-Bis[4-(2-ethylhexyl)oxycarbonylphenyl]benzamidine

실험 절차

N,N'-Bis[4-(2-ethylhexyl)oxycarbonylphenyl]benzamidine (3) was prepared from 2-ethylhexyl 4-aminobenzoate and α,α,α-trichlorotoluene; viscous, gold oil: 1H-NMR (CDCl3) 7.9-6.8 (m, 14H), 4.1 (d, 4H, J=4 Hz), 1.9-0.8 (m, 30H); IR (Neat) 3330, 1710, 1585; MS (m/e) 584 (M+), 336 (base).

출처 및 근거

ORD 기록: ord-1259a049dafe4236b03801955abaa1d3
출처 데이터셋: uspto-grants-1991_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05011628

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