Carbon Disulfide → HCID 14651794, 화합물
반응식
[CH2:1]([C:8]#N)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7].[CH3:10][NH:11][CH2:12][CH2:13][NH2:14].C(=S)=S>C(OCC)(=O)C>[CH3:10][N:11]1[CH2:12][CH2:13][N:14]=[C:8]1[CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7]참가 물질
5
반응 조건
- 온도
- 125 °C
실험 절차
14.207 g (113.46 mmoles) of heptyl cyanide, 10.726 g (144.69 mmoles) of N-methylethylenediamine and 0.5 ml of carbon disulfide were mixed and heated at 125° C. for 24 hours. The solution was cooled, diluted with ethyl acetate and extracted with dilute hydrochloric acid. The acidic solution was basified with sodium hydroxide and extracted with ethyl acetate. The organic extracts were treated with charcoal, filtered, concentrated and Kugelrohr distilled at 105° C./1.2 mm to give 19.73 g (77.3%) of the product.
후처리
- temperatureThe solution was cooled
- extractionextracted with dilute hydrochloric acid
- extractionextracted with ethyl acetate
- additionThe organic extracts were treated with charcoal
- filtrationfiltered
- concentrationconcentrated
- distillationKugelrohr distilled at 105° C./1.2 mm
출처 및 근거
- ORD 기록
- ord-d6997c8cf6ed41e5a05bcb7568a6f02f
- 출처 데이터셋
- uspto-grants-1991_07
- 특허 번호
- US05030629
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