N-(2-Hydroxyethyl)ethylenediamine → Octyl hydroxyethyl imidazoline

HRID 1086433

반응식

HRID 1086433 반응식
[CH2:1]([C:9]#N)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[NH2:11][CH2:12][CH2:13][NH:14][CH2:15][CH2:16][OH:17]>C(=S)=S>[OH:17][CH2:16][CH2:15][N:14]1[CH2:13][CH2:12][N:11]=[C:9]1[CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

참가 물질

4

반응물 2

HCID 8112N-(2-Hydroxyethyl)ethylenediamineHCID 16715Nonanenitrile

생성물 1

HCID 117550Octyl hydroxyethyl imidazoline수율 62.7%

시약·촉매·용매 1

HCID 6348Carbon Disulfide용매

실험 절차

13.02 g (93.51 mmoles) of octyl cyanide was treated with 12.327 g (118.36 mmoles) of 2-(2-aminoethylamino)ethanol in presence of 0.5 ml of carbon disulfide at 125° C. for 24 hrs. and worked up as outlined under Example 23. Distillation of the residue at 167°-169° C./0.5 mm gave 12.332 g (62.7%) of product.

후처리

  1. distillationDistillation of the residue at 167°-169° C./0.5 mm

출처 및 근거

ORD 기록
ord-8aa60d48881043c1aec24d3113c0485e
출처 데이터셋
uspto-grants-1991_07
특허 번호
US05030629

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