Dimethylformamide → HCID 57930995, 화합물

HRID 1096984노트

반응식

HRID 1096984 반응식
[CH2:1](I)[CH3:2].CN(C=O)C.[Br:9][C:10]1[C:19]([O:20][CH3:21])=[CH:18][C:13]([C:14]([O:16][CH3:17])=[O:15])=[CH:12][C:11]=1[OH:22].C(=O)([O-])[O-].[K+].[K+]>O>[Br:9][C:10]1[C:19]([O:20][CH3:21])=[CH:18][C:13]([C:14]([O:16][CH3:17])=[O:15])=[CH:12][C:11]=1[O:22][CH2:1][CH3:2]

참가 물질

6

반응물 4

HCID 6228DimethylformamideHCID 6340IodoethaneHCID 11430Potassium CarbonateHCID 57930973HCID 57930973, 화합물

생성물 1

HCID 57930995HCID 57930995, 화합물

시약·촉매·용매 1

HCID 962Water용매

실험 절차

In a 1.0-liter egg plant-type flaks, ethyl iodide (6.91 mL, 86 mmol) was added to a DMF (150 mL) solution of the previously-obtained methyl 4-bromo-3-hydroxy-5-methoxybenzoate and potassium carbonate (11.9 g, 86 mmol), and stirred overnight at room temperature. Water was added to the reaction solution, the formed precipitate was taken out through filtration and dried under reduced pressure to obtain the title compound as a colorless solid.

후처리

  1. filtrationthe formed precipitate was taken out through filtration
  2. customdried under reduced pressure

출처 및 근거

ORD 기록
ord-764ac02837e64c8ab08283cb874b6954
출처 데이터셋
uspto-grants-2012_03
특허 번호
US08138197B2

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