Sodium Chloride → p-Diethylaminoethylstyrene Divinylbenzene

HRID 1106133

반응식

HRID 1106133 반응식
[Cl-].[Na+].S([O-])(OCC[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])(=O)=O.[Na+].[CH2:21]([N:23]([CH2:26][CH2:27][C:28]1[CH:35]=[CH:34][C:31]([CH:32]=[CH2:33])=[CH:30][CH:29]=1)[CH2:24][CH3:25])[CH3:22].C(C1C=CC=CC=1C=C)=C.C(C1C=CC=CC=1)(=O)C.C(OCC)(=O)C1C=CC=CC=1.N(C(C)(C)C#N)=NC(C)(C)C#N>O>[CH2:21]([N:23]([CH2:26][CH2:27][C:28]1[CH:29]=[CH:30][C:31]([CH:32]=[CH2:33])=[CH:34][CH:35]=1)[CH2:24][CH3:25])[CH3:22].[CH:17]([C:16]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1[CH:10]=[CH2:9])=[CH2:18]

참가 물질

9

반응물 7

HCID 5234Sodium ChlorideHCID 6547AzobisisobutyronitrileHCID 7165Ethyl benzoateHCID 7410AcetophenoneHCID 666661,2-DiethenylbenzeneHCID 3015378N,N-Diethyl-p-vinylphenethylamineHCID 3423265Sodium Lauryl Sulfate

생성물 1

HCID 131712650p-Diethylaminoethylstyrene Divinylbenzene

시약·촉매·용매 1

HCID 962Water용매

실험 절차

Into a 500 ml four necked flask were charged 6 g of hydroxyapatite, 3 g of sodium chloride, 0.3 g of sodium lauryl sulfate and 330 g of pure water, and the mixture was added a mixture of 12.8 g of the same p-diethylaminoethylstyrene as prepared in Synthesis 1, 7.2 g of the same divinylbenzene as in Example 1, 20 g of acetophenone, 20 g of ethyl benzoate and 0.3 g of 2,2'-azobisisobutyronitrile under stirring. Then the mixture was stirred at 60° C. for 1 hour, at 70° C. for 2 hours and further at 80° C. for 4 hours. The copolymer in the form of particles thus obtained was thoroughly washed with water on a 300 mesh sieve and repeatedly washed with acetone using a glass filter. Then part of the copolymer was subjected to vacuum drying at 60° C. for 8 hours. The porous structure of the copolymer dried were measured by a mercury penetration porosimeter.

후처리

  1. additionthe mixture was added
  2. stirringThen the mixture was stirred at 60° C. for 1 hour, at 70° C. for 2 hours and further at 80° C. for 4 hours
  3. customThe copolymer in the form of particles thus obtained
  4. washwas thoroughly washed with water on a 300 mesh sieve
  5. washrepeatedly washed with acetone using a glass
  6. filtrationfilter
  7. customdrying at 60° C. for 8 hours
  8. customThe porous structure of the copolymer dried

출처 및 근거

ORD 기록
ord-68e77b5d36024023a2ef0d8d4fca52da
출처 데이터셋
uspto-grants-1982_01
특허 번호
US04311799

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