2-Octanol → Propan-2-yl 2-dodecylbenzene-1-sulfonate

HRID 1109090

반응식

HRID 1109090 반응식
CC(O)CCCCCC.[CH2:10]([C:22]1C=CC=C[C:23]=1S(Cl)(=O)=O)[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]CC.[C:32]1(C)[CH:37]=[CH:36][C:35]([S:38]([O:41][CH:42]([CH3:49])[CH2:43]CCCCC)(=[O:40])=[O:39])=[CH:34][CH:33]=1>>[CH2:19]([C:34]1[CH:33]=[CH:32][CH:37]=[CH:36][C:35]=1[S:38]([O:41][CH:42]([CH3:43])[CH3:49])(=[O:39])=[O:40])[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:22][CH3:23]

참가 물질

4

반응물 3

HCID 200832-OctanolHCID 3912199HCID 3912199, 화합물HCID 204390012-Dodecylbenzene-1-sulfonyl chloride

생성물 1

HCID 23368822Propan-2-yl 2-dodecylbenzene-1-sulfonate수율 83%

실험 절차

In the Example of preparation of material 18, 2-octanol was used in place of 2-propanol in the Example of preparation of material 17. In the Example of preparation of material 19, dodecylbenzene sulfonyl chloride was used in place of p-toluene sulfonyl chloride in the Example of preparation of material 17. Other procedures were made in the same way as the Example of preparation of material 17. In the Example of preparation of material 18, 1-methylheptyl p-toluene sulfonate was obtained in the yield of 72% and, in the Example of preparation of material 19, 1-methylethyl dodecylbenzene sulfonate was obtained in the yield of 83%.

출처 및 근거

ORD 기록
ord-fcde6d5423e74d30ae06c643be62027b
출처 데이터셋
uspto-grants-1994_06
특허 번호
US05319024

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