Carbon Dioxide → 2,6-Dichlorophenyl sulfamate

HRID 1109981

반응식

HRID 1109981 반응식
O.[Cl:2][C:3]1[CH:15]=[CH:14][CH:13]=[C:12]([Cl:16])[C:4]=1[O:5][S:6]([N:9]=C=O)(=[O:8])=[O:7].C(=O)=O>ClC(Cl)(Cl)Cl>[S:6](=[O:8])(=[O:7])([O:5][C:4]1[C:3]([Cl:2])=[CH:15][CH:14]=[CH:13][C:12]=1[Cl:16])[NH2:9]

참가 물질

5

반응물 3

HCID 280Carbon DioxideHCID 962WaterHCID 190184682,6-Dichlorophenoxysulfonyl isocyanate

생성물 1

HCID 190184672,6-Dichlorophenyl sulfamate

시약·촉매·용매 1

HCID 5943Carbon Tetrachloride용매

반응 조건

온도
0 °C

실험 절차

2.6 ml of water are added dropwise at 30° C. to 40° C. to a solution of 24.4 g of 2,6-dichlorophenoxysulfonyl isocyanate in 200 ml of tetrachloromethane. The mixture is then stirred at room temperature until the evolution of carbon dioxide is complete and cooled to 0° C., the product is filtered off with suction and the residue is then washed with ice-cold tetrachloromethane. After drying in vacuo, 21.4 g of 2,6-dichlorophenyl sulfamate of melting point 108°-110° C. are obtained.

후처리

  1. filtrationthe product is filtered off with suction
  2. washthe residue is then washed with ice-cold tetrachloromethane
  3. dry with materialAfter drying in vacuo, 21.4 g of 2,6-dichlorophenyl sulfamate of melting point 108°-110° C.
  4. customare obtained

출처 및 근거

ORD 기록
ord-e54d7659cfb745089cd80515edce33e1
출처 데이터셋
uspto-grants-1994_06
특허 번호
US05324710

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