1-(Hexyloxy)-2-nitrobenzene → 2-(Hexyloxy)aniline

HRID 1110429노트

반응식

HRID 1110429 반응식
[CH2:1]([O:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[N+:14]([O-])=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].[H][H]>CO.[Ni]>[CH2:1]([O:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[NH2:14])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

참가 물질

5

반응물 2

HCID 150681131-(Hexyloxy)-2-nitrobenzeneHCID 178418361HCID 178418361, 화합물2회

생성물 1

HCID 159374522-(Hexyloxy)aniline

시약·촉매·용매 2

HCID 935Nickel촉매HCID 887Methanol용매

실험 절차

1-(Hexyloxy)-2-nitrobenzene, 61.28 g (0.27 mol) is dissolved in 700 ml of methanol, 3 g Raney nickel is added and the mixture exposed to hydrogen gas until the required amount of hydrogen is absorbed. The methanol solution is filtered and concentrated in vacuo and the residue distilled to give 50 g of 2-(hexyloxy)benzenamine; bp 145°-148° C. at 4 mm.

후처리

  1. customis absorbed
  2. filtrationThe methanol solution is filtered
  3. concentrationconcentrated in vacuo
  4. distillationthe residue distilled

출처 및 근거

ORD 기록
ord-b65654df64f84755832fadaf785add3c
출처 데이터셋
uspto-grants-1990_12
특허 번호
US04975456

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