Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Hydrochloric Acid → N-(allyloxycarbonyl)glycine methyl ester
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Hydrochloric Acid | HCID 313 | — |
| 반응물 | Sodium Bicarbonate | HCID 516892 | — |
| 반응물 | N-[(allyloxy)carbonyl]glycine | HCID 11964402 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | N-(allyloxycarbonyl)glycine methyl ester | HCID 22154858 | — |
반응 단계
A solution of 0.06 mol of N-(allyloxycarbonyl)glycine, prepared as described by F. Guibe, O. Dangles, and G. Balavione in Tetrahedron Letters, 1986, 27, 2365-2368, and 0.066 mol of HCl in 100 mL of CH3OH is stirred at reflux for 8 hours. The solution is then cooled and treated with 0.066 mol of sodium bicarbonate. The solvent is removed by rotary evaporator, and the residue is dissolved in diethyl ether, filtered, dried over MgSO4, and filtered. The solvent is removed by rotary evaporator to give N-(allyloxycarbonyl)glycine methyl ester.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04977272 |
| 출처 데이터셋 | uspto-grants-1990_12 |
| ORD ID | ord-c6d3ef9add384eb29b0cd1b055b59e8a |
| 출처 메모 | uspto-grants-1990_12 |