Aluminum(III) Chloride → trans-1-Benzoyl-4-phenyl-l-proline

HRID 1165976

반응식

HRID 1165976 반응식
[C:1]([N:9]1[CH2:16][C@@H:15](OS(C2CCCCC2)(=O)=O)[CH2:14][C@H:10]1[C:11]([OH:13])=[O:12])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Cl-].[Al+3].[Cl-].[Cl-]>C1C=CC=CC=1>[C:1]([N:9]1[CH2:16][C@H:15]([C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)[CH2:14][C@H:10]1[C:11]([OH:13])=[O:12])(=[O:8])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

참가 물질

4

반응물 2

HCID 6451240Aluminum(III) ChlorideHCID 14750339(cis)-1-benzoyl-4-[(cyclohexylsulfonyl)oxy]-L-proline

생성물 1

HCID 46864073trans-1-Benzoyl-4-phenyl-l-proline

시약·촉매·용매 1

HCID 241Benzene용매

실험 절차

Following the procedure outlined in Example 2C, (cis)-1-benzoyl-4-[(cyclohexylsulfonyl)oxy]-L-proline was treated with aluminum chloride and benzene to afford a mixture consisting of:

후처리

  1. customto afford a mixture

출처 및 근거

ORD 기록
ord-b1f10ceadbde45f1be38d97325c56326
출처 데이터셋
uspto-grants-1990_03
특허 번호
US04912231

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