Trifluoromethanesulfonic acid → Diphenyliodonium trifluoromethanesulfonate

HRID 1168019노트

반응식

HRID 1168019 반응식
COP([O-])(OC)=O.[C:8]1([I+:14][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1.[F:21][C:22]([F:28])([F:27])[S:23]([OH:26])(=[O:25])=[O:24]>C(Cl)Cl>[O-:26][S:23]([C:22]([F:28])([F:27])[F:21])(=[O:25])=[O:24].[C:15]1([I+:14][C:8]2[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=2)[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=1

참가 물질

4

반응물 2

HCID 62406Trifluoromethanesulfonic acidHCID 22995015Diphenyliodonium dimethylphosphate

생성물 1

HCID 2737137Diphenyliodonium trifluoromethanesulfonate수율 72%

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

Diphenyliodonium dimethylphosphate (315 mg; 1 mmol) and trifluoromethanesulfonic acid (158 mg; 1.01 mmol) were dissolved in methylene chloride (10 ml), and the resultant mixture was stirred. Half volume of the solvent was removed from the methylene chloride solution through distillation, and ether (50 ml) was added thereto. The mixture was stirred, to thereby precipitate 109 mg of the target compound as white crystals (yield: 72%).

후처리

  1. customHalf volume of the solvent was removed from the methylene chloride solution through distillation, and ether (50 ml)
  2. additionwas added

출처 및 근거

ORD 기록
ord-0f20c81ad4654943958ba708f4ecdfd9
출처 데이터셋
uspto-grants-2003_09
특허 번호
US06620957B1

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