Acrylic Acid → Bis(2-hydroxyphenyl)methane

HRID 1169540

반응식

HRID 1169540 반응식
C([C:5]1[CH:10]=[CH:9][C:8](C)=[C:7]([OH:12])[C:6]=1[CH2:13][CH2:14][CH2:15][CH3:16])CCC.[C:17](O)(=[O:20])[CH:18]=[CH2:19].[Cl-].C[NH+](C)C>C1(C)C=CC=CC=1>[CH:16]1[CH:15]=[C:14]([CH2:13][C:6]2[C:7]([OH:12])=[CH:8][CH:9]=[CH:10][CH:5]=2)[C:17]([OH:20])=[CH:18][CH:19]=1

참가 물질

5

반응물 3

HCID 6581Acrylic AcidHCID 11649Trimethylazanium;chlorideHCID 20226228Dibutylhydroxy toluene

생성물 1

HCID 75575Bis(2-hydroxyphenyl)methane

시약·촉매·용매 1

HCID 1140Toluene용매

반응 조건

온도
98 °C

실험 절차

Bisphenol F epoxy resin (Nihon Kayaku Co., Ltd. RE-404P, epoxy equivalent 160 g/eq., amount of hydrolysis 30 ppm) was dissolved in toluene, and added dibutylhydroxy toluene as the polymerization inhibitor therein, then temperature was risen up to 60° C. Thereafter, acrylic acid in 100% equivalent amount to epoxy group was added, further temperature was risen up to 80° C. Then trimethylammonium chloride as the reaction catalyst was added thereto, followed by stirring at 98° C. for about 50 hours. The resultant reaction mixture was washed with water, and toluene was distilled out to obtain epoxy acrylate of bisphenol F (Epoxyacrylate C).

후처리

  1. customas the polymerization inhibitor therein, then temperature
  2. customwas risen up to 60° C
  3. customwas risen up to 80° C
  4. customThe resultant reaction mixture
  5. washwas washed with water, and toluene
  6. distillationwas distilled out

출처 및 근거

ORD 기록
ord-65553c8be1584eafa7d45bda73d4bd69
출처 데이터셋
uspto-grants-2010_11
특허 번호
US07824746B2

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