Vinyltrichlorosilane → 1,1,1,4,4-Pentachloro-1,4-disilabutane

HRID 1172047

반응식

HRID 1172047 반응식
[CH:1]([Si:3]([Cl:6])([Cl:5])[Cl:4])=[CH2:2].[Cl:7][SiH2:8][Cl:9]>[CH-]=O.[CH-]=O.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Co].[Co+2]>[Cl:4][Si:3]([Cl:6])([Cl:5])[CH2:1][CH2:2][SiH:8]([Cl:9])[Cl:7]

참가 물질

4

반응물 2

HCID 6413VinyltrichlorosilaneHCID 61330Dichlorosilane

생성물 1

HCID 1019294941,1,1,4,4-Pentachloro-1,4-disilabutane수율 108%

시약·촉매·용매 1

HCID 25049Dicobalt Octacarbonyl (stabilized with 1-5% Hexane)촉매

반응 조건

온도
0 °C

실험 절차

Vinyltrichlorosilane (68.8 g, 426 mmol) and cobalt octacarbonyl (700 mg) were placed in a 100 mL rb flask and cooled in an ice bath to 0° C. Dichlorosilane (bp. 8° C., 44.3 g, 439 mmol) was then condensed into the flask, The system was allowed to warm up to room temperature during night. Distillation at 60 . . . 62° C./8 mbar gave 1,1,1,4,4-Pentachloro-1,4-disilabutane (120.8 g, 460 mmol) in 93% yield.

후처리

  1. customcondensed into the flask
  2. temperatureto warm up to room temperature during night
  3. distillationDistillation at 60

출처 및 근거

ORD 기록
ord-7cb81af7f20344d7848b45a4dcfc5c70
출처 데이터셋
uspto-grants-2010_11
특허 번호
US07833820B2

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