Water → N-[(2,4,6-Trimethylbenzene-1-sulfonyl)oxy]propan-2-imine

HRID 1182267노트

반응식

HRID 1182267 반응식
[C:1]1([CH3:13])[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[S:9](Cl)(=[O:11])=[O:10].[CH3:14][C:15](=[N:17][OH:18])[CH3:16].O>N1C=CC=CC=1>[CH3:13][C:1]1[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[S:9]([O:18][N:17]=[C:15]([CH3:16])[CH3:14])(=[O:11])=[O:10]

참가 물질

5

반응물 3

HCID 962WaterHCID 130462-Mesitylenesulfonyl chlorideHCID 67180Acetone, oxime

생성물 1

HCID 279802N-[(2,4,6-Trimethylbenzene-1-sulfonyl)oxy]propan-2-imine

시약·촉매·용매 1

HCID 1049Pyridine용매

실험 절차

To a solution of mesitylenesulfonyl chloride (2.0 g, 9.05 mmol) in pyridine (30 mL) was added acetone oxime (0.67 g, 9.05 mmol), and the solution was stirred under N2 for 16 hours. It was poured into 500 ml of water and stirred for 1 hour. The precipitate was filtered and dried Acetone O-(2,4,6-trimethylphenylsulfonyl)oxime was obtained as white powder (57.6%) yield.

후처리

  1. stirringstirred for 1 hour
  2. filtrationThe precipitate was filtered

출처 및 근거

ORD 기록
ord-9d90ae9d63cc44f2baa2f64a3f172a1c
출처 데이터셋
uspto-grants-2007_10
특허 번호
US07288538B2

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