Acetic Acid → 2,6-Diacetoxynaphthalene

HRID 1194594

반응식

HRID 1194594 반응식
[OH:1][C:2]1[CH:11]=[CH:10][C:9]2[C:4](=[CH:5][CH:6]=[C:7]([OH:12])[CH:8]=2)[CH:3]=1.[C:13](OC(=O)C)(=[O:15])[CH3:14].[C:20](O)(=[O:22])[CH3:21]>>[C:13]([O:1][C:2]1[CH:11]=[CH:10][C:9]2[C:4](=[CH:5][CH:6]=[C:7]([O:12][C:20](=[O:22])[CH3:21])[CH:8]=2)[CH:3]=1)(=[O:15])[CH3:14]

참가 물질

4

반응물 3

HCID 176Acetic AcidHCID 7918Acetic AnhydrideHCID 935522,6-Dihydroxynaphthalene

생성물 1

HCID 5949302,6-Diacetoxynaphthalene수율 91.7%

실험 절차

Thereafter, a mixture of 33.2 g (0.187 mole) of the thus obtained 2,6-dihydroxynaphthalene, 15.0 g of acetic acid and 44.9 g of acetic anhydride was stirred for 90 min in an oil bath kept at 140° C. After the reaction was over, the reaction mixture was cooled to room temperature and the thus precipitated crystals were collected by filtration, washed with acetic acid and dried to obtain 41.8 g of 2,6-diacetoxynaphthalene of white in color in a yield of 91.7%.

후처리

  1. customkept at 140° C
  2. filtrationthe thus precipitated crystals were collected by filtration
  3. washwashed with acetic acid
  4. customdried

출처 및 근거

ORD 기록
ord-a35b8b79b62442b49115615029a110fb
출처 데이터셋
uspto-grants-1989_03
특허 번호
US04814521

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