Perilla alcohol → Perilla alcohol

HRID 1195186

반응식

HRID 1195186 반응식
[CH3:1][C:2]([C@@H:4]1[CH2:9][CH:8]=[C:7]([CH2:10][OH:11])[CH2:6][CH2:5]1)=[CH2:3]>O.C(O)C(O)C.OCC(CO)O>[CH3:3][C:2]([C@@H:4]1[CH2:5][CH:6]=[C:7]([CH2:10][OH:11])[CH2:8][CH2:9]1)=[CH2:1].[CH3:10][C:7]1[CH2:8][CH2:9][C@@H:4]([C:2]([CH3:3])=[CH2:1])[CH2:5][CH:6]=1

참가 물질

6

반응물 1

HCID 369312Perilla alcohol2회

생성물 2

HCID 369312Perilla alcoholHCID 440917(+)-Limonene

시약·촉매·용매 3

HCID 753Glycerol용매HCID 962Water용매HCID 1030Propylene Glycol용매

실험 절차

Perillyl alcohol is an oil with a terpenic aroma. It is insoluble in water, is poorly soluble in propylene glycol, and is almost insoluble in glycerine. Perillyl alcohol is soluble in alcohol and is miscible in oil. It is used as a flavoring agent for cosmetics and perfumes, but heretofore, it has not been used as a bactericide. Perillyl alcohol can be produced by the oxidation of limonene as was demonstrated by Blumann in Chemical Abstracts, Volume 63, 1965 on page 1819, and Bardychev in Chemical Abstracts, Volume 80, 1974, page 359. It can be produced by the acetylation of limonene as described by Ansari, Hifzure R. (German Offen 2,513,910 and Canadian Patent No. 1,077,959). Walling made perillyl alcohol (Canadian Patent No. 981,695) from beta pinene by adding benzyl peroxide to beta pinene followed by alkaline hydrolysis to perillyl alcohol.

출처 및 근거

ORD 기록
ord-b35cbd246ae24975bec1314e01d4eae7
출처 데이터셋
uspto-grants-1992_05
특허 번호
US05110832

연결된 노트

불러오는 중…