Benzyl Chloride → Benzyldiphenylamine

HRID 1197239

반응식

HRID 1197239 반응식
[CH2:1](OC1C=CC=CC=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:15]1([NH:21][C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.C(Cl)C1C=CC=CC=1>O>[C:22]1([N:21]([C:15]2[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=2)[CH2:1][C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=1

참가 물질

5

반응물 3

HCID 7503Benzyl ChlorideHCID 11487DiphenylamineHCID 70352Benzyl Phenyl Ether

생성물 1

HCID 69080Benzyldiphenylamine

시약·촉매·용매 1

HCID 962Water용매

실험 절차

N-phenylbanzaldimine (1.81 g, 0.010 mol) and benzylphenyl ether (1.84 g, 0.010 mol) were heated at 75° C. in Na/DMF solution (2.0 g; 50 mL) for 30 minutes. The solution was then poured in 200 mL of water, the precipitate was filtered washed with water and dried. Recrystallization from methanol, 70 mL, gave white needles (73% isolated) mp 88°-90° C. (lit mp 86°-7°C8, 88°-9°C9). No depression in melting point occurred when this material was admixed with an authentic sample prepared from diphenylamine and benzyl chloride.

후처리

  1. filtrationthe precipitate was filtered
  2. washwashed with water
  3. customdried
  4. customRecrystallization from methanol, 70 mL
  5. customgave white
  6. customneedles (73% isolated) mp 88°-90° C. (lit mp 86°-7°C8, 88°-9°C9)

출처 및 근거

ORD 기록
ord-b56cadaf1ab140f5b653791f41ed18d3
출처 데이터셋
uspto-grants-1992_05
특허 번호
US05117062

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