Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium Iodide → Silane, (5-iodo-1-pentynyl)trimethyl-
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium Iodide | HCID 5238 | — |
| 반응물 | 1-Chloro-5-(trimethylsilyl)-4-pentyne | HCID 2757942 | — |
| 용매 | Methyl Ethyl Ketone | HCID 6569 | — |
| 생성물 | Silane, (5-iodo-1-pentynyl)trimethyl- | HCID 11140046 | 93.8% |
반응 단계
A mixture of 5-chloro-1-trimethylsilylpent-1-yne (13.5 g) and sodium iodide (29 g) in butanone (100 ml) was heated at reflux for 10 hours. After this time the solvent was removed in vacuo and the residue partitioned between diethyl ether and water. The organic phase was separated, washed with water and brine before drying over anhydrous magnesium sulphate. The solvent was removed under reduced pressure to leave 5-iodo-1-trimethylsilylpent-1-yne as a colourless oil (19.3 g).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05116862 |
| 출처 데이터셋 | uspto-grants-1992_05 |
| ORD ID | ord-c4231ee7bb5640f5a60a84c9ecb89209 |
| 출처 메모 | uspto-grants-1992_05 |