Thiophene-3,4-dicarboxylic acid → 1H,3H-Thieno[3,4-c]furan-1,3-dione

HRID 1197419

반응식

HRID 1197419 반응식
[S:1]1[CH:5]=[C:4]([C:6]([OH:8])=O)[C:3]([C:9]([OH:11])=[O:10])=[CH:2]1>C(OC(=O)C)(=O)C>[S:1]1[CH:2]=[C:3]2[C:9]([O:11][C:6](=[O:8])[C:4]2=[CH:5]1)=[O:10]

참가 물질

3

반응물 1

HCID 255853Thiophene-3,4-dicarboxylic acid

생성물 1

HCID 3156081H,3H-Thieno[3,4-c]furan-1,3-dione수율 98%

시약·촉매·용매 1

HCID 7918Acetic Anhydride용매

실험 절차

Thiophene-3,4-dicarboxylic acid (12 g, 0.07 mol) is dissolved in acetic anhydride (60 ml) and heated at the boil for 2.5 hours. The mixture is then evaporated to dryness. 10.55 g (98%) of thiophene-3,4-dicarboxylic anhydride (mp. 147° to 149° C.) are obtained.

후처리

  1. temperatureheated at the boil for 2.5 hours
  2. customThe mixture is then evaporated to dryness

출처 및 근거

ORD 기록
ord-d9e5436240564df6a2c11da402a92143
출처 데이터셋
uspto-grants-1994_01
특허 번호
US05276009

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