Benzene → N-(4-methoxyphenyl)-4-nitro-3-methylbenzene carboximidoyl chloride

HRID 1197868

반응식

HRID 1197868 반응식
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([NH:9][C:10](=O)[C:11]2[CH:16]=[CH:15][C:14]([N+:17]([O-:19])=[O:18])=[C:13]([CH3:20])[CH:12]=2)=[CH:5][CH:4]=1.C1C=CC=CC=1.S(Cl)([Cl:30])=O>>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([N:9]=[C:10]([Cl:30])[C:11]2[CH:16]=[CH:15][C:14]([N+:17]([O-:19])=[O:18])=[C:13]([CH3:20])[CH:12]=2)=[CH:5][CH:4]=1

참가 물질

4

반응물 3

HCID 241BenzeneHCID 24386Thionyl ChlorideHCID 790964N-(4-methoxyphenyl)-3-methyl-4-nitrobenzamide

생성물 1

HCID 13633435N-(4-methoxyphenyl)-4-nitro-3-methylbenzene carboximidoyl chloride

실험 절차

14 g of N-(4-methoxyphenyl)-4-nitro-3-methyl benzamide in suspension in 70 ml of thionyl chloride were heated for 20 hours at reflux. The solvent was eliminated by entrainment with benzene, and after drying under reduced pressure at ambient temperature, 15 g of N-(4-methoxyphenyl)-4-nitro-3-methylbenzene carboximidoyl chloride melting towards 80° C. were obtained.

후처리

  1. temperatureat reflux
  2. customafter drying under reduced pressure at ambient temperature

출처 및 근거

ORD 기록
ord-d6a32888520145e7b0f7ea42659d374a
출처 데이터셋
uspto-grants-1994_01
특허 번호
US05278180

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