Hydrochloric Acid → Bistrifluoromethylarsine
반응식
Cl.I[As:3]([C:8]([F:11])([F:10])[F:9])[C:4]([F:7])([F:6])[F:5]>[Zn].O>[F:5][C:4]([AsH:3][C:8]([F:11])([F:10])[F:9])([F:7])[F:6]참가 물질
5
실험 절차
The trifluoromethyl arsine hydrides can be made via direct reaction of the tris-trifluoromethyl arsenic iodides with zinc and hydrochloric acid. For instance, 10 g of zinc, 10 ml of water, and 15 ml of 5N HCl are shaken with 3.80 g of iodo bis-trifluoromethylarsine to give 1.03 g of bistrifluoromethylarsine (b.p. 19° C.), a 43% yield. Trifluoromethylarsine can be made by a similar method (b.p. -12.5° C.).
출처 및 근거
- ORD 기록
- ord-ae1182a47e97489a8be4469a14a3dc06
- 출처 데이터셋
- uspto-grants-1990_02
- 특허 번호
- US04904616
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