Ammonia → 6-Hydroxyhexanenitrile

반응식

[C:1]1(=[O:8])O[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[NH3:9]>>[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][C:6]#[N:9].[OH:8][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][C:6]#[N:9]

참가 물질

반응물 2

HCID 222Ammonia

HCID 10401epsilon-CAPROLACTONE

생성물 2

HCID 1232225-Hexenenitrile수율 22%

HCID 118153226-Hydroxyhexanenitrile수율 24%

실험 절차

The reaction of epsilon-caprolactone with ammonia in the gas phase over alumina gives 22% of hex-1-ene-6-nitrile and 24% of epsilon-hydroxycapronitrile.

출처 및 근거

ORD 기록: ord-dcb328a092a94b17aaad6a03b053683f
출처 데이터셋: uspto-grants-1990_02
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04904812

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