Dihydrocholesterol → (+)-2-Octanol

반응식

[CH3:1][C@@H:2]([OH:9])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].C[C@H]1[C@H](O)C[C@H]2C(C)(C)[C@@H]1C2.CC1C(O)CC2C(C)(C)C1C2.C[C@@H]([C@@H]1[C@@]2(C)CC[C@@H]3[C@@]4(C)CC[C@H](O)C[C@@H]4CC[C@H]3[C@@H]2CC1)CCCC(C)C.C[C@@H]([C@@H]1[C@@]2(C)CC[C@@H]3[C@@]4(C)CC[C@@H](O)C[C@@H]4CC[C@H]3[C@@H]2CC1)CCCC(C)C>>[CH3:1][C@H:2]([OH:9])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

참가 물질

반응물 5

HCID 6665Dihydrocholesterol

HCID 66066Epidihydrocholesterin

HCID 80080(R)-2-Octanol

HCID 99038Bicyclo(3.1.1)heptan-3-ol, 2,6,6-trimethyl-, (1alpha,2beta,3alpha,5alpha)-

HCID 10524983(-)-Isopinocampheol

생성물 1

HCID 2723888(+)-2-Octanol

실험 절차

(R)-2-octanol (6a), Example 13: (1S, 2S, 3S, 5R)-(−)-isopinocampheol (7a), Example 14: (1R, 2R, 3R, 5S)-(−)-isopiriocampheol (8a), Example 15: β-cholestanol (9a) and Example 16: α-cholestanol (10a).

출처 및 근거

ORD 기록: ord-01e058a412e6466dbf4d0c99dcb191ea
출처 데이터셋: uspto-grants-2006_10
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07125725B2

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