Hydrochloric Acid → Benzenesulfonyl azide

HRID 1248969

반응식

HRID 1248969 반응식
[C:1]1([S:7]([NH:10][NH2:11])(=[O:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.Cl.[N:13]([O-])=O.[Na+]>O>[C:1]1([S:7]([N:10]=[N+:11]=[N-:13])(=[O:8])=[O:9])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

참가 물질

5

반응물 3

HCID 313Hydrochloric AcidHCID 65723Benzenesulfonyl hydrazideHCID 23668193Sodium Nitrite

생성물 1

HCID 555606Benzenesulfonyl azide

시약·촉매·용매 1

HCID 962Water용매2회

실험 절차

26.3 g of benzenesulphonohydrazide, 100 ml of water, 21 ml of 10N hydrochloric acid and 1.3 g of Emulgator ED (a fatty alcohol/ethylene oxide addition product) are stirred for 30 minutes, 60 g of ice are added and a solution of 19.5 g of sodium nitrite in 50 ml of water is then added dropwise in the course of about 30 minutes. The batch is stirred for 30 minutes, excess nitrite is then destroyed with a small amount of sulphamic acid, and excess acid is neutralised with about 5 ml of 10N sodium hydroxide solution. An emulsion of benzenesulphonyl azide is obtained.

후처리

  1. stirringThe batch is stirred for 30 minutes
  2. customexcess nitrite is then destroyed with a small amount of sulphamic acid, and excess acid

출처 및 근거

ORD 기록
ord-8f01ea04d696485cbe1795f7e1370b1c
출처 데이터셋
uspto-grants-1986_12
특허 번호
US04628082

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